The synthesis of the following compound has to be illustrated using benzene as the starting compound. Concept Introduction: Electrophilic substitution reactions of aromatic compounds are known as aromatic electrophilic substitution reactions. An electrophile is a species that is deficient of electrons . Benzene is an electron rich Aromatic compound . It undergoes aromatic electrophilic substitution reaction. The delocalized nature of pi electrons in benzene attributes a special property to benzene called resonance. The various types of electrophilic substitution reactions in benzene are – Chlorination, Bromination, Nitration, Sulfonation, Friedel Crafts Alkylation/Acylation etc. Apart from electrophilic substitution reactions benzene and its derivatives also undergo another special type of reactions namely Aromatic nucleophilic substitution reactions. The criteria for aromatic nucleophilic substitution reaction to occur are – The aromatic ring must contain a strong electron withdrawing group The aromatic ring must contain a leaving group The leaving group must be posited either ortho or para position to the strong electron withdrawing group.

Question

Want to see the full answer?

Answer 1

Question

Chapter 19.13, Problem 36CC

Interpretation Introduction

Interpretation:

The synthesis of the following compound has to be illustrated using benzene as the starting compound.

Concept Introduction:

Electrophilic substitution reactions of aromatic compounds are known as aromatic electrophilic substitution reactions. An electrophile is a species that is deficient of electrons.

Benzene is an electron rich Aromatic compound. It undergoes aromatic electrophilic substitution reaction. The delocalized nature of pi electrons in benzene attributes a special property to benzene called resonance.

The various types of electrophilic substitution reactions in benzene are – Chlorination, Bromination, Nitration, Sulfonation, Friedel Crafts Alkylation/Acylation etc.

Apart from electrophilic substitution reactions benzene and its derivatives also undergo another special type of reactions namely Aromatic nucleophilic substitution reactions.

The criteria for aromatic nucleophilic substitution reaction to occur are –

The aromatic ring must contain a strong electron withdrawing group

The aromatic ring must contain a leaving group

The leaving group must be posited either ortho or para position to the strong electron withdrawing group.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5

2H2S(g)+3O2(g)→2SO2(g)+2H2O(g) A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion. Question Which of the following predicts the theoretical yield of SO2(g) from the reaction? Responses 1.2 g Answer A: 1.2 grams A 41 g Answer B: 41 grams B 77 g Answer C: 77 grams C 154 g Answer D: 154 grams D

Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10