For the classification of matter, the incompatible structural term has to be chosen from the given options. Concept Introduction: Atoms of the element are the smallest particle that exists which has the properties of the element. If a group of atoms that is relatively small but bound together means it is known as molecule. Molecules can be classified into various types. Diatomic molecule is a type of molecule that contains two atoms. The two atoms may be of same element or different element. Triatomic molecule is a type of molecule that contains three atoms. The three atoms may be from a same element or different element. This series goes on like this as tetraatomic, pentaatomic molecules etc. If the molecules are to be classified on basis of observation then two types can be given. Homoatomic molecules are the ones that have the atoms of same kind in the molecule. Molecule that contains same type of atoms in it has to be an element. Heteroatomic molecule is the one that contains two or more kinds of atoms in a molecule.

Question

Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 1

Question

Chapter 1.9, Problem 4QQ

Interpretation Introduction

Interpretation:

For the classification of matter, the incompatible structural term has to be chosen from the given options.

Concept Introduction:

Atoms of the element are the smallest particle that exists which has the properties of the element. If a group of atoms that is relatively small but bound together means it is known as molecule.

Molecules can be classified into various types. Diatomic molecule is a type of molecule that contains two atoms. The two atoms may be of same element or different element. Triatomic molecule is a type of molecule that contains three atoms. The three atoms may be from a same element or different element. This series goes on like this as tetraatomic, pentaatomic molecules etc.

If the molecules are to be classified on basis of observation then two types can be given. Homoatomic molecules are the ones that have the atoms of same kind in the molecule. Molecule that contains same type of atoms in it has to be an element. Heteroatomic molecule is the one that contains two or more kinds of atoms in a molecule.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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