Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Chapter 19, Problem 48RQ
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Complete combustion of a 0.6250 g sample of the unknown crystal with excess O2 produced 1.8546 g of CO2 and 0.5243 g of H2O. A separate analysis of a 0.8500 g sample of the blue crystal was found to produce 0.0465 g NH3. The molar mass of the substance was found to be about 310 g/mol. What is the molecular formula of the unknown crystal?
4. C6H100
5
I peak
3
2
PPM
Integration values: 1.79ppm (2), 4.43ppm (1.33)
Ipeak
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Chapter 19 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 19 - Sketch and label a galvanic cell that makes use of...Ch. 19 - Write the anode and cathode half-reactions for the...Ch. 19 - Copper metal and zinc metal will both reduce Ag+...Ch. 19 - A galvanic cell has a standard cell potential of...Ch. 19 - Using the positions of the respective...Ch. 19 - Use the positions of the half-reactions in Table...Ch. 19 - What are the overall cell reaction and the...Ch. 19 - What are the overall cell reaction and the...Ch. 19 - A 1.0 M solution of copper(II) perchlorate and 1.0...Ch. 19 - A galvanic cell is constructed with two platinum...
Ch. 19 - Prob. 11PECh. 19 - Under standard state conditions, which of the...Ch. 19 - A certain reaction has an Ecello of 0.107 volts...Ch. 19 - Calculate G for the reactions that take place in...Ch. 19 - The calculated standard cell potential for the...Ch. 19 - Use the following half-reactions and the data in...Ch. 19 - A galvanic cell is constructed with a copper...Ch. 19 - In Example 19.9, assume all conditions are the...Ch. 19 - In the analysis of two other water samples by the...Ch. 19 - A galvanic cell is constructed with a copper...Ch. 19 - In the electrolysis of an aqueous solution...Ch. 19 - In the electrolysis of an aqueous solution...Ch. 19 - How many moles of hydroxide ion will be produced...Ch. 19 - How many minutes will it take for a current of...Ch. 19 - What current must be supplied to deposit 0.0500 g...Ch. 19 - Suppose the solutions in the galvanic cell...Ch. 19 - Galvanic Cells What is a galvanic cell? What is a...Ch. 19 - Galvanic Cells
19.2 What is the function of a salt...Ch. 19 - Galvanic Cells In a coppersilver cell, why must...Ch. 19 - Galvanic Cells What is the general name we give to...Ch. 19 - Galvanic Cells In a galvanic cell, do electrons...Ch. 19 - Galvanic Cells Explain how the movement of the...Ch. 19 - Galvanic Cells
19.7 Aluminum will displace tin...Ch. 19 - Galvanic Cells
19.8 Make a sketch of the galvanic...Ch. 19 - Galvanic Cells 19.9 Make a sketch of a galvanic...Ch. 19 - Galvanic Cells Make a sketch of a galvanic cell...Ch. 19 - Prob. 11RQCh. 19 - Cell Potentials How are standard reduction...Ch. 19 - If you set up a galvanic cell using metals not...Ch. 19 - Cell Potentials Galvanic cells are set up so that...Ch. 19 - Utilizing Standard Reduction Potentials Describe...Ch. 19 - Utilizing Standard Reduction Potentials What do...Ch. 19 - Prob. 17RQCh. 19 - Utilizing Standard Reduction Potentials Describe...Ch. 19 - Prob. 19RQCh. 19 - Prob. 20RQCh. 19 -
19.21 What is the equation that relates the...Ch. 19 - EcelloandG Show how the equation that relates the...Ch. 19 - Ecello and G What is the cell potential of a...Ch. 19 - Cell Potentials and Concentration 19.24 The cell...Ch. 19 - Cell Potentials and Concentration What is a...Ch. 19 - Cell Potentials and Concentration Describe what...Ch. 19 - Electricity What are the anode and cathode...Ch. 19 - Prob. 28RQCh. 19 - Electricity
19.29 How is a hydrometer constructed?...Ch. 19 - lectricity What reactions occur at the electrodes...Ch. 19 - Electricity
19.31 What chemical reactions take...Ch. 19 - Prob. 32RQCh. 19 - Electricity
19.33 What are the anode, cathode, and...Ch. 19 - Electricity Give two reasons why lithium is such...Ch. 19 - Electricity What are the electrode materials in a...Ch. 19 - Electricity
19.36 What are the electrode materials...Ch. 19 - Prob. 37RQCh. 19 - Electricity Write the cathode, anode, and net cell...Ch. 19 - Electricity What advantages do fuel cells offer...Ch. 19 - Electrolytic Cells What electrical charges do the...Ch. 19 - Electrolytic Cells
19.41 Why must electrolysis...Ch. 19 - Electrolytic Cells Why must NaCl be melted before...Ch. 19 - Electrolytic Cells Write half-reactions for the...Ch. 19 - Electrolytic Cells
19.44 What happens to the pH of...Ch. 19 - Electrolysis Stoichiometry
19.45 What is a...Ch. 19 - Electrolysis Stoichiometry
19.46 Using the same...Ch. 19 - Electrolysis Stoichiometry
19.47 An electric...Ch. 19 - Electrolysis Stoichiometry
19.48 An electric...Ch. 19 - Practical Applications of Electrolysis What is...Ch. 19 - Practical Applications of Electrolysis
19.50...Ch. 19 - Practical Applications of Electrolysis In the...Ch. 19 - Prob. 52RQCh. 19 - Practical Applications of Electrolysis Describe...Ch. 19 - Prob. 54RQCh. 19 - Galvanic Cells Write the half-reactions and the...Ch. 19 - Galvanic Cells Write the half-react ions and the...Ch. 19 - Write the cell notation for the following galvanic...Ch. 19 - Write the cell notation for the following galvanic...Ch. 19 - For each pair of substances, use Table 19.l to...Ch. 19 - 19.60 For each pair of substances, use Table 19.1...Ch. 19 - Use the data in Table 19.1 to calculate the...Ch. 19 - 19.62 Use the data in Table 19.1 to calculate the...Ch. 19 - From the positions of the half-reactions in Table...Ch. 19 - Use the data in Table 19.1 to determine which of...Ch. 19 - 19.65 From the half-reactions below, determine the...Ch. 19 - 19.66 What is the standard cell potential and the...Ch. 19 - What will be the spontaneous reaction among...Ch. 19 - What will be the spontaneous reaction among...Ch. 19 - Will the following reaction occur spontaneously...Ch. 19 - Determine whether the reaction:...Ch. 19 -
19.71 Calculate for the following reaction as...Ch. 19 - EcellandG Calculate G for the reaction...Ch. 19 - Given the following half-reactions and their...Ch. 19 - Calculate Kc for the system Ni2++CoNi+Co2+ Use the...Ch. 19 - 19.75 The system
has a calculated What is the...Ch. 19 - Determine the value of Kc at 25C for the reaction...Ch. 19 - Cell Potentials and Concentrations 19.77 The cell...Ch. 19 - Cell Potentials and Concentrations
19.78 The for...Ch. 19 - *19.79 A cell was set up having the following...Ch. 19 - A silver wire coated with AgCl is sensitive to the...Ch. 19 - At 25C, a galvanic cell was set up having the...Ch. 19 - *19.82 Suppose a galvanic cell was constructed at ...Ch. 19 - *19.83 What is the potential of a concentration...Ch. 19 - *19.84 What is the potential of a concentration...Ch. 19 - Prob. 85RQCh. 19 - Prob. 86RQCh. 19 - What products would we expect at the electrodes if...Ch. 19 - What products would we expect at the electrodes if...Ch. 19 - Using Table 19.1, list the ions in aqueous...Ch. 19 - Prob. 90RQCh. 19 - Electrolysis Stoichiometry
19.91 How many moles of...Ch. 19 - Electrolysis Stoichiometry
19.92 How many moles of...Ch. 19 - 19.93 How many grams of Fe(OH)2 are produced at an...Ch. 19 - 19.94 How many grams of would be produced in the...Ch. 19 - Prob. 95RQCh. 19 - 19.96 How many hours would it take to generate...Ch. 19 - 19.97 How many amperes would be needed to produce...Ch. 19 - 19.98 A large electrolysis cell that produces...Ch. 19 - *19.99 The electrolysis of 250 mL of a brine...Ch. 19 - *19.100 A 100.0 mL sample of 2.00MNaCl was...Ch. 19 - *19.101 A watt is a unit of electrical power and...Ch. 19 - Suppose that a galvanic cell were set up having...Ch. 19 - Prob. 103RQCh. 19 - *19.104 The value of for AgBr is . What will be...Ch. 19 - 19.105 Based only on the half-reactions in Table...Ch. 19 - A student set up an electrolysis apparatus and...Ch. 19 - *19.107 A hydrogen electrode is immersed in a 0.10...Ch. 19 - *19.108 What current would be required to deposit ...Ch. 19 - *19.109 A solution containing vanadium in an...Ch. 19 - Consider the reduction potentials of the following...Ch. 19 - An Ag/AgCl electrode dipping into 1.00MHCl has a...Ch. 19 - Prob. 112RQCh. 19 - Consider the following galvanic cell:...Ch. 19 - The electrolysis of 0.250 L of a brine solution...Ch. 19 - A solution of NaCl in water was electrolyzed with...Ch. 19 - How many milliliters of dry gaseous H2, measured...Ch. 19 - *19.117 At , a galvanic cell was set up having the...Ch. 19 - Given the following reduction half-reactions and...Ch. 19 - The normal range of chloride ions in blood serum...Ch. 19 - An unstirred solution of 2.00 M NaCl was...Ch. 19 - What masses of and O2 in grams would have to react...Ch. 19 - *19.122 Draw an atomic-level diagram of the events...Ch. 19 - *19.123 In biochemical systems, the normal...Ch. 19 - Calculate a new version of Table 19.1 using the...Ch. 19 - In Problem 19.83, the potential at 75C was...Ch. 19 - There are a variety of methods available for...Ch. 19 - *19.128 Most flashlights use two or more batteries...Ch. 19 - 19.129 If two electrolytic cells are placed in...Ch. 19 - Prob. 130RQCh. 19 - Prob. 131RQ
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- 3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…arrow_forwardA chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.arrow_forwardNonearrow_forward
- in which spectral range of EMR, atomic and ionic lines of metal liesarrow_forwardQ2: Label the following molecules as chiral or achiral, and label each stereocenter as R or S. CI CH3 CH3 NH2 C CH3 CH3 Br CH3 X &p Bra 'CH 3 "CH3 X Br CH3 Me - N OMe O DuckDuckarrow_forward1. For the four structures provided, Please answer the following questions in the table below. a. Please draw π molecular orbital diagram (use the polygon-and-circle method if appropriate) and fill electrons in each molecular orbital b. Please indicate the number of π electrons c. Please indicate if each molecule provided is anti-aromatic, aromatic, or non- aromatic TT MO diagram Number of π e- Aromaticity Evaluation (X choose one) Non-aromatic Aromatic Anti-aromatic || ||| + IVarrow_forward
- 1.3 grams of pottasium iodide is placed in 100 mL of o.11 mol/L lead nitrate solution. At room temperature, lead iodide has a Ksp of 4.4x10^-9. How many moles of precipitate will form?arrow_forwardQ3: Circle the molecules that are optically active: ДДДДarrow_forward6. How many peaks would be observed for each of the circled protons in the compounds below? 8 pts CH3 CH3 ΤΙ A. H3C-C-C-CH3 I (₁₁ +1)= 7 H CI B. H3C-C-CI H (3+1)=4 H LIH)=2 C. (CH3CH2-C-OH H D. CH3arrow_forward
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