Given the following half-reactions and E o values, M n 3 + ( a q ) + e − → M n 2 + ( a q ) E o = 1.54 V M n O 2 ( s ) + 4 H + ( a q ) + e − → M n 3 + ( a q ) + 2 H 2 O ( l ) E o = 0.95 V write a balanced equation for the formation of M n 2 + and MnO 2 from M n 3 + , and calculate the value of E o for this reaction. Is the reaction spontaneous under standard-state conditions?
Given the following half-reactions and E o values, M n 3 + ( a q ) + e − → M n 2 + ( a q ) E o = 1.54 V M n O 2 ( s ) + 4 H + ( a q ) + e − → M n 3 + ( a q ) + 2 H 2 O ( l ) E o = 0.95 V write a balanced equation for the formation of M n 2 + and MnO 2 from M n 3 + , and calculate the value of E o for this reaction. Is the reaction spontaneous under standard-state conditions?
Solution Summary: The author explains that the balanced equation for the overall cell reaction and the value of E° of the reaction under standard state conditions needs to be determined.
Given the following half-reactions and Eo values,
M
n
3
+
(
a
q
)
+
e
−
→
M
n
2
+
(
a
q
)
E
o
=
1.54
V
M
n
O
2
(
s
)
+
4
H
+
(
a
q
)
+
e
−
→
M
n
3
+
(
a
q
)
+
2
H
2
O
(
l
)
E
o
=
0.95
V
write a balanced equation for the formation of
M
n
2
+
and MnO2 from
M
n
3
+
, and calculate the value of
E
o
for this reaction. Is the reaction spontaneous under standard-state conditions?
Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C.
Mg(s) ∣ Mg2+(aq, 2.74 M) || Cu2+(aq, 0.0033 M) ∣ Cu(s)
Calculate E° for Ni(glycine)2 + 2e– D Ni + 2 glycine– given
Ni2+ + 2 glycine– D Ni(glycine)2 K = 1.2×1011
Ni2+ + 2 e– D Ni E° = -0.236 V
One method for the analysis of Fe3+, which is used with a variety of sample matrices, is to form the highly colored Fe3+–thioglycolic acid complex. The complex absorbs strongly at 535 nm. Standardizing the method is accomplished using external standards. A 10.00-ppm Fe3+ working standard is prepared by transferring a 10-mL aliquot of a 100.0 ppm stock solution of Fe3+ to a 100-mL volumetric flask and diluting to volume. Calibration standards of 1.00, 2.00, 3.00, 4.00, and 5.00 ppm are prepared by transferring appropriate amounts of the 10.0 ppm working solution into separate 50-mL volumetric flasks, each of which contains 5 mL of thioglycolic acid, 2 mL of 20% w/v ammonium citrate, and 5 mL of 0.22 M NH3. After diluting to volume and mixing, the absorbances of the external standards are measured against an appropriate blank. Samples are prepared for analysis by taking a portion known to contain approximately 0.1 g of Fe3+, dissolving it in a minimum amount of HNO3, and diluting to…
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell