(a) Interpretation: The synthesis of 4 − methyl − 3 − heptanol starting from a compound containing five or fewer carbon is to be stated. Concept introduction: Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

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Answer 1

Question

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol). a) Write a balanced net reaction that can occur between species in this solution. b) Calculate deltaG0 and K for the reaction. c) Calculate E and deltaG for the conditions given. Ce4+ + e- = Ce3+ E0= 1.70 V MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V

1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in the following reaction. Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is a weak base used to neutralize strong acid (pKa < 0) produced by the reaction. Redraw the product to show the configuration(s) that form at C-2 and C-4. Br2 OH CH2Cl2 Na* HCO3 Br HO OH + Na Br +

2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O2/HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI + enant OH Solvent Reagent(s) Solvent Reagent(s)

Answer 2

Question

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

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Answer 3

Question

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

Expert Solution & Answer

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Answer 4

Question

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

Expert Solution & Answer

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Answer 5

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

Answer 6

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Answer 7

Chapter 19, Problem 19.65AP

Interpretation Introduction

(a)

Interpretation:

The synthesis of 4−methyl−3−heptanol starting from a compound containing five or fewer carbon is to be stated.

Concept introduction:

Pheromones are natural substances produced and released by animals. They are used by organisms for communicating or signaling. They are also used by insects to mark trails in defense, to show readiness for mating.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the compound 4−methyl−3−heptanol appears to be a mixture of isomers is to be stated.

Concept introduction:

Isomers are the compounds having the same molecular formula but differ in the arrangements of atoms and molecules. The stereoisomer is two or more compounds that differ in the spatial arrangement of the atoms

Answer 10

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Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

Solution Summary: The author explains that pheromones are natural substances produced and released by animals and are used by insects to mark trails in defense, to show readiness for mating.

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