(a) Interpretation: The major organic product for the reaction is to be drawn. Concept introduction: An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

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Answer 1

Question

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.

Answer 2

Question

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

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Answer 3

Question

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

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Answer 4

Question

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

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Answer 5

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

Answer 6

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Answer 7

Chapter 19, Problem 19.62P

Interpretation Introduction

(a)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The major organic product for the reaction is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes.

Answer 10

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

Solution Summary: The author explains that an alkene metathesis occurs when one or more alkines are treated with Grubbs catalyst, which contains a Ru=C bond.

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