4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Question

9. OA. Rank the expected boiling points of the compounds shown below from highest to lowest. Place your answer appropriately in the box. Only the answer in the box will be graded. (3) points) OH OH بر بد بدید 2 3

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

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9. OA. Rank the expected boiling points of the compounds shown below from highest to lowest. Place your answer appropriately in the box. Only the answer in the box will be graded. (3) points) OH OH بر بد بدید 2 3

There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…

A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ M

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

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Answer 5

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 6

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 7

Chapter 19, Problem 19.46P

(a)

Interpretation Introduction

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 8

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 9

(b)

Interpretation Introduction

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 10

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 11

(c)

Interpretation Introduction

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 12

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 13

(d)

Interpretation Introduction

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 14

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 15

(e)

Interpretation Introduction

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 16

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 17

(f)

Interpretation Introduction

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 18

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 19

(g)

Interpretation Introduction

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 20

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 21

(h)

Interpretation Introduction

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Answer 22

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Answer 23

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Answer 24

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Answer 27

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Answer 28

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Answer 33

Ch. 19.2 - Prob. 19.1P Ch. 19.2 - Prob. 19.2P Ch. 19.2 - Prob. 19.3P Ch. 19.3 - Prob. 19.4P Ch. 19.3 - Prob. 19.5P Ch. 19.3 - Prob. 19.6P Ch. 19.5 - Prob. 19.7P Ch. 19.5 - Prob. 19.8P Ch. 19.5 - Prob. 19.9P Ch. 19.6 - Prob. 19.10P

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: 4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: 2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: 3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: 2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: 4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: 3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation: Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Chapter 19 Solutions

Interpretation:

4-phenyl-2-butanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

2-methylhexanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

3-ethyl-2-pentanone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

2-propyl-1,3-propanediol has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

4-oxopentanoic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

3-benzyl-5-hexen-2-one has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

Cyclopropane carboxylic acid has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.

Interpretation:

Cyclobutylmethyl ketone has to be synthesized either by acetoacetic ester synthesis or malonic ester synthesis.