A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed. Concept Introduction: Alkylation of diethyl malonate: The acidity of α − hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows S N 2 path way.

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Answer 1

Question

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

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SYNTHESIS REACTIONS. For the following reactions, synthesize the given products from the given reactants. Multiple reactions/steps will be needed. For the one of the steps (ie reactions) in each synthesis, write out the mechanism for that reaction and draw an energy diagram showing the correct number of hills and valleys for that step's mechanism. CI b. a. Use acetylene (ethyne) and any alkyl halide as your starting materials Br C. d. "OH OH III. OH

Answer 2

Question

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

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Answer 3

Question

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

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Answer 4

Question

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

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Answer 5

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

Answer 6

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

Answer 7

Chapter 19, Problem 19.44P

(a)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

Answer 8

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

Answer 9

(b)

Interpretation Introduction

Interpretation:

A reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

Concept Introduction:

Alkylation of diethyl malonate:

The acidity of $α−$ hydrogens between the two carbonyl groups plays an important rule for alkylation of diethyl malonate. The addition of haloalkanes follows $SN2$ path way.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19.2 - Prob. 19.1P Ch. 19.2 - Prob. 19.2P Ch. 19.2 - Prob. 19.3P Ch. 19.3 - Prob. 19.4P Ch. 19.3 - Prob. 19.5P Ch. 19.3 - Prob. 19.6P Ch. 19.5 - Prob. 19.7P Ch. 19.5 - Prob. 19.8P Ch. 19.5 - Prob. 19.9P Ch. 19.6 - Prob. 19.10P

Solution Summary: The author explains that a reaction sequence for the synthesis of the given derivatives of diethyl malonate has to be proposed.

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Chapter 19 Solutions