ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 19, Problem 19.3P
Draw the structure corresponding to each common name.
a.
b.
c.
d.
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Instructions: Draw out each compound to clearly show what groups are bonded to the carbonyl carbon.
Label each compound as a carboxylic acid, ester, or amide.
a. CH3CH2CO2CH2CH3
b. CH3CONHCH3
c. (CH3)3CCO2H
d. (CH3)2CHCON(CH3)2
Instructions: Give the IUPAC name for each compound.
A.
CH₂
CH₂CH₂CH₂CCH₂COOH
CH3
B.
CH₂CHCH₂CH₂COOH
CH₂COOH
CH₂CH3
C. (CH,CH,),CHCH,CHCOOH
Instructions: Give the structure corresponding to each IUPAC name.
a. 2-bromobutanoic acid
b. 2,3-dimethylpentanoic acid
c. 2-ethyl-5,5-dimethyloctanoic acid
d. 3,4,5,6-tetraethyldecanoic acid
What kind of solvent ingredients is usually used in the concentrations of 4-10 percent in skin care products and their function is to soften skin cells and to lessen wrinkles?
A. Ethly acetate
B. Alpha hydroxyl acids
C. Phenols and phenol derivatives
D. Aliphatic alcohols
Give an acceptable name for these compounds.
Chapter 19 Solutions
ORGANIC CHEMISTRY
Ch. 19 - Prob. 19.1PCh. 19 - Problem 19.2 Give the structure corresponding to...Ch. 19 - Problem 19.3 Draw the structure corresponding to...Ch. 19 - Prob. 19.4PCh. 19 - Prob. 19.5PCh. 19 - Problem 19.6 Rank the following compounds in order...Ch. 19 - Problem 19.7 Explain how you could use IR...Ch. 19 - Prob. 19.8PCh. 19 - Problem 19.9 How many tetrahedral stereogenic...Ch. 19 - Problem 19.10 What alcohol can be oxidized to each...
Ch. 19 - Problem 19.11 Identify A-D in the following...Ch. 19 - Problem 9.12 Draw the cation that results when a...Ch. 19 - Problem 19.13 Draw the products of each acid-base...Ch. 19 - Problem 19.14 Given the values in Appendix A,...Ch. 19 - Problem 19.15 Rank the labeled protons in...Ch. 19 - Problem 19.16 Match each of the following values ...Ch. 19 - Problem 19.17 Rank the compounds in each group in...Ch. 19 - Problem 19.18 Rank the compounds in each group in...Ch. 19 - Prob. 19.19PCh. 19 - Problem 19.20 Which of the following pairs of...Ch. 19 - Problem 19.21 Two other commonly used sulfonic...Ch. 19 - Problem 19.22 Draw both enantiomers of each amino...Ch. 19 - Problem 19.23 Explain why amino acids, unlike most...Ch. 19 - Problem 19.24 Draw the positively charged,...Ch. 19 - Prob. 19.25PCh. 19 - Problem 19.26 Explain why the of the group of...Ch. 19 - Answer each question for A and B depicted in the...Ch. 19 - Prob. 19.28PCh. 19 - 19.29 Give the IUPAC name for each compound.
a....Ch. 19 - 19.30 Draw the structure corresponding to each...Ch. 19 - Prob. 19.31PCh. 19 - 19.32 Rank the following compounds in order of...Ch. 19 - 19.33 Draw the organic products formed in each...Ch. 19 - 19.34 Identify the lettered compounds in each...Ch. 19 - 19.35 Using the table in Appendix A, determine...Ch. 19 - 19.36 Draw the products of each acid-base...Ch. 19 - 19.37 Which compound in each pair has the lower ?...Ch. 19 - 19.38 Rank the compounds in each group in order of...Ch. 19 - 19.39 Rank the compounds in each group in order of...Ch. 19 - 19.40 Match the values to the appropriate...Ch. 19 - Prob. 19.41PCh. 19 - 19.42 Which carboxylic acid has the lower ,...Ch. 19 - Prob. 19.43PCh. 19 - 19.44 Explain the following statement. Although...Ch. 19 - Prob. 19.45PCh. 19 - 19.46 Explain why the of compound A is lower than...Ch. 19 - 19.47 Rank the following compounds in order of...Ch. 19 - Prob. 19.48PCh. 19 - Prob. 19.49PCh. 19 - 19.50 Draw all resonance structures of the...Ch. 19 - As we will see in Chapter 23, CH bonds are...Ch. 19 - Prob. 19.52PCh. 19 - The pKa of acetamide (CH3CONH2) is 16. Draw the...Ch. 19 - 19.54 Write out the steps needed to separate...Ch. 19 - Prob. 19.55PCh. 19 - Can octane and octan -1- ol be separated using an...Ch. 19 - 19.57 Identify each compound from its spectral...Ch. 19 - 19.58 Use the NMR and IR spectra given below to...Ch. 19 - 19.59 An unknown compound (molecular formula )...Ch. 19 - 19.60 Propose a structure for (molecular formula...Ch. 19 - 19.61 Match the data to the appropriate...Ch. 19 - Prob. 19.62PCh. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - 19.65 For each amino acid ,draw its neutral,...Ch. 19 - Calculate the isoelectric point for each amino...Ch. 19 - 19.67 Lysine and tryptophan are two amino acids...Ch. 19 - Prob. 19.68PCh. 19 - Prob. 19.69PCh. 19 - Prob. 19.70PCh. 19 - 19.71 Hydroxy butanedioic acid occurs naturally in...Ch. 19 - 19.72 Although it was initially sold as a rat...
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- QUESTION 1 Which of the following compounds has an activating group? A. Benzoic acid B. None in the answer C. Bromobenzene D. Diphenylamine QUESTION 2 Which of the following compounds has a deactivating group attached to the benzene ring? A. Toluene B. Acetanilide C. Phenol D. Salicyclic Acidarrow_forwardDraw the structure corresponding to each name. a. propyl formate b. butyl butanoate c. heptyl benzoate d. N-ethylhexanamide e. N-ethyl- N-methylheptanamidearrow_forwardWhich of the following compounds will NOT test positive in a hydroxamic test? a. butanoic acid b. butanoyl chloride c. butyl ethanoate d. butanoic acid anhydridearrow_forward
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