
Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Chapter 19, Problem 19.126QA
Interpretation Introduction
To determine:
The molecules which do not have any possible stereoisomers
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 19 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 19 - Prob. 19.1VPCh. 19 - Prob. 19.2VPCh. 19 - Prob. 19.3VPCh. 19 - Prob. 19.4VPCh. 19 - Prob. 19.5VPCh. 19 - Prob. 19.6VPCh. 19 - Prob. 19.7VPCh. 19 - Prob. 19.8VPCh. 19 - Prob. 19.9VPCh. 19 - Prob. 19.10VP
Ch. 19 - Prob. 19.11VPCh. 19 - Prob. 19.12VPCh. 19 - Prob. 19.13QACh. 19 - Prob. 19.14QACh. 19 - Prob. 19.15QACh. 19 - Prob. 19.16QACh. 19 - Prob. 19.17QACh. 19 - Prob. 19.18QACh. 19 - Prob. 19.19QACh. 19 - Prob. 19.20QACh. 19 - Prob. 19.21QACh. 19 - Prob. 19.22QACh. 19 - Prob. 19.23QACh. 19 - Prob. 19.24QACh. 19 - Prob. 19.25QACh. 19 - Prob. 19.26QACh. 19 - Prob. 19.27QACh. 19 - Prob. 19.28QACh. 19 - Prob. 19.29QACh. 19 - Prob. 19.30QACh. 19 - Prob. 19.31QACh. 19 - Prob. 19.32QACh. 19 - Prob. 19.33QACh. 19 - Prob. 19.34QACh. 19 - Prob. 19.35QACh. 19 - Prob. 19.36QACh. 19 - Prob. 19.37QACh. 19 - Prob. 19.38QACh. 19 - Prob. 19.39QACh. 19 - Prob. 19.40QACh. 19 - Prob. 19.41QACh. 19 - Prob. 19.42QACh. 19 - Prob. 19.43QACh. 19 - Prob. 19.44QACh. 19 - Prob. 19.45QACh. 19 - Prob. 19.46QACh. 19 - Prob. 19.47QACh. 19 - Prob. 19.48QACh. 19 - Prob. 19.49QACh. 19 - Prob. 19.50QACh. 19 - Prob. 19.51QACh. 19 - Prob. 19.52QACh. 19 - Prob. 19.53QACh. 19 - Prob. 19.54QACh. 19 - Prob. 19.55QACh. 19 - Prob. 19.56QACh. 19 - Prob. 19.57QACh. 19 - Prob. 19.58QACh. 19 - Prob. 19.59QACh. 19 - Prob. 19.60QACh. 19 - Prob. 19.61QACh. 19 - Prob. 19.62QACh. 19 - Prob. 19.63QACh. 19 - Prob. 19.64QACh. 19 - Prob. 19.65QACh. 19 - Prob. 19.66QACh. 19 - Prob. 19.67QACh. 19 - Prob. 19.68QACh. 19 - Prob. 19.69QACh. 19 - Prob. 19.70QACh. 19 - Prob. 19.71QACh. 19 - Prob. 19.72QACh. 19 - Prob. 19.73QACh. 19 - Prob. 19.74QACh. 19 - Prob. 19.75QACh. 19 - Prob. 19.76QACh. 19 - Prob. 19.77QACh. 19 - Prob. 19.78QACh. 19 - Prob. 19.79QACh. 19 - Prob. 19.80QACh. 19 - Prob. 19.81QACh. 19 - Prob. 19.82QACh. 19 - Prob. 19.83QACh. 19 - Prob. 19.84QACh. 19 - Prob. 19.85QACh. 19 - Prob. 19.86QACh. 19 - Prob. 19.87QACh. 19 - Prob. 19.88QACh. 19 - Prob. 19.89QACh. 19 - Prob. 19.90QACh. 19 - Prob. 19.91QACh. 19 - Prob. 19.92QACh. 19 - Prob. 19.93QACh. 19 - Prob. 19.94QACh. 19 - Prob. 19.95QACh. 19 - Prob. 19.96QACh. 19 - Prob. 19.97QACh. 19 - Prob. 19.98QACh. 19 - Prob. 19.99QACh. 19 - Prob. 19.100QACh. 19 - Prob. 19.101QACh. 19 - Prob. 19.102QACh. 19 - Prob. 19.103QACh. 19 - Prob. 19.104QACh. 19 - Prob. 19.105QACh. 19 - Prob. 19.106QACh. 19 - Prob. 19.107QACh. 19 - Prob. 19.108QACh. 19 - Prob. 19.109QACh. 19 - Prob. 19.110QACh. 19 - Prob. 19.111QACh. 19 - Prob. 19.112QACh. 19 - Prob. 19.113QACh. 19 - Prob. 19.114QACh. 19 - Prob. 19.115QACh. 19 - Prob. 19.116QACh. 19 - Prob. 19.117QACh. 19 - Prob. 19.118QACh. 19 - Prob. 19.119QACh. 19 - Prob. 19.120QACh. 19 - Prob. 19.121QACh. 19 - Prob. 19.122QACh. 19 - Prob. 19.123QACh. 19 - Prob. 19.124QACh. 19 - Prob. 19.125QACh. 19 - Prob. 19.126QACh. 19 - Prob. 19.127QACh. 19 - Prob. 19.128QACh. 19 - Prob. 19.129QACh. 19 - Prob. 19.130QACh. 19 - Prob. 19.131QACh. 19 - Prob. 19.132QACh. 19 - Prob. 19.133QACh. 19 - Prob. 19.134QACh. 19 - Prob. 19.135QACh. 19 - Prob. 19.136QACh. 19 - Prob. 19.137QACh. 19 - Prob. 19.138QACh. 19 - Prob. 19.139QACh. 19 - Prob. 19.140QACh. 19 - Prob. 19.141QACh. 19 - Prob. 19.142QA
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