Identify each of the following half-reaction as either an oxidation half-reaction or a reduction half-reaction:
Write a balanced equation for the overall
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- Write balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.arrow_forwardGold can be dissolved from gold-bearing rock by treating the rock with sodium cyanide in the presence of oxygen. 4 Au(s) + 8 NaCN(aq) + O2(g) + 2 H2O() 4 NaAu(CN)2(aq) + 4 NaOH(aq) (a) Name the oxidizing and reducing agents in this reaction. What has been oxidized, and what has been reduced? (b) If you have exactly one metric ton (1 metric ton = 1000 kg) of gold-bearing rock, what volume of 0.075 M NaCN, in liters, do you need to extract the gold if the rock is 0.019% gold?arrow_forwardAssign an oxidation number to the underlined atom in each ion or molecule. (a) Fe2O3, (b) H2SO4, (C) CO32- (C) NO2+arrow_forward
- Consider these half-reactions: (a) Which is the weakest oxidizing agent? (b) Which is the strongest oxidizing agent? (c) Which is the strongest reducing agent? (d) Which is the weakest reducing agent? (e) Will Sn(s) reduce Ag+(aq) to Ag(s)? (f) Will Hg() reduce Sn2+(aq) to Sn(s)? (g) Name the ions that can be reduced by Sn(s). (h) Which metals can be oxidized by Ag+(aq)?arrow_forwardOrder the following oxidizing agents by increasing strength under standard-state conditions: Mg2+(aq), Hg2+(aq), Pb2+(aq).arrow_forwardAn electrode is prepared from liquid mercury in contact with a saturated solution of mercury(I) chloride, Hg2Cl, containing 1.00 M Cl . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.268 V. What is the solubility product of mercury(I) chloride?arrow_forward
- Consider the following cell running under standard conditions: Fe(s)Fe2+(aq)Al3+(aq)Al(s) a Is this a voltaic cell? b Which species is being reduced during the chemical reaction? c Which species is the oxidizing agent? d What happens to the concentration of Fe3+(aq) as the reaction proceeds? e How does the mass of Al(s) change as the reaction proceeds?arrow_forwardFour metals, A, B, C, and D, exhibit the following properties: (a) Only A and C react with 1.0 M hydrochloric acid to give H2(g). (b) When C is added to solutions of the ions of the other metals, metallic B, D, and A are formed. (c) Metal D reduces Bn+ to give metallic B and Dn+. Based on this information, arrange the four metals in order of increasing ability to act as reducing agents.arrow_forwardWrite balanced equations for the following half-reactions. Specify whether each is an oxidation or reduction. (a) H2O2(aq) O2(g)(in acid) (b) H2C2O4(aq) CO2(g)(in acid) (c) NO3(aq) NO(g)(in acid) (d) MnO4(aq) MnO2(s)(in base)arrow_forward
- An electrolytic cell is set up with Cd(s) in Cd(NO3)2(aq) and Zn(s) in Zn(NO3)2(aq). Initially both electrodesweigh 5.00 g. After running the cell for several hours theelectrode in the left compartment weighs 4.75 g. (a) Which electrode is in the left compartment? (b) Does the mass of the electrode in the right compartmentincrease, decrease, or stay the same? If the masschanges, what is the new mass? (c) Does the volume of the electrode in the right compartment increase, decrease, or stay the same? If the volumechanges, what is the new volume? (The density of Cd is8.65 g/cm3.)arrow_forwardOne of the few industrial-scale processes that produce organic compounds electrochemically is used by the Monsanto Company to produce1,4-dicyanobutane. The reduction reaction is 2CH2CHCH+2H++2eNC(CH2)4CN The NC(CH2)4CN is then chemically reduced using hydrogen gas to H2N(CH2)6NH2, which is used in the production of nylon. What current must be used to produce 150.kg NC(CH2)4CN per hour?arrow_forwardThe blood alcohol (C2H5OH) level can be determined by titrating a sample of blood plasma with an acidic potassium di-chromate solution, resulting in the production of Cr3+ (aq) and carbon dioxide. The reaction can be monitored because the dichromate ion (Cr2O72) is orange in solution, and the Cr3+ ion is green. The balanced equations is 16H+(aq) + 2Cr2O72(aq) + C2H5OH(aq) 4Cr4+(aq) + 2CO2(g) + 11H2O(l) This reaction is an oxidationreduction reaction. What species is reduced, and what species is oxidized? How many electrons are transferred in the balanced equation above?arrow_forward
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