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Chemistry
- Which of the following is true for a particular reaction if AG° is -40.0 kJ/mol at 290 K and -20.0 kJ/mol at 390 K? A) ΔΗ >0 , ΔS 0 Β) ΔΗ 0, AS< 0 D) ΔΗ < 0, ΔS 0 E) None of these +arrow_forwardThe Ksp for a very insoluble salt is 4.2 x 10-47 at 298 K. Whatis ΔG° for the dissolution of the salt in water?(a) -265 kJ/mol (b) -115 kJ/mol (c) -2.61 kJ/mol(d) +115 kJ/mol (e) +265 kJ/molarrow_forwardQUESTION 22 At what temperature, in Kelvin, does the following reaction change from spontaneous to non-spontaneous 2 A (aq) + 2 B (aq) 2 C (aq) + 1 D (aq) if AH° (A)= 0.8219 kJ/mol, AH° (B) = -40.5308 kJ/mol, AH° (C) = -85.3178 kJ/mol, and AH (D) = -70 8643 kJ/mol AS (A)= 76.117 J/(mol K), AS (B) = -15.8072 J/(mol K), AS (C) = 18.4425 J/(mol K), and AS" (D) = -8.6387 J/(mol K)arrow_forward
- The ΔG°rxn for this reaction is -107.8 kJ/mol. Given the values for ΔGf°; what is the ΔGf° for A2B(l)? 2AC(g) + B2(g) → A2B(l) + BC2(g) Substance ΔGf° (kJ/mol) AC(g) -174.3 B2(g) 173.3 BC2(g) 169.9arrow_forwardWhat happens to ΔG°298 (becomes more negative or more positive) for the following chemical reactions when the partial pressure of oxygen is increased?(a) S(s) + O2(g) ⟶ SO2(g)(b) 2SO2(g) + O2(g) ⟶ SO3(g)(c) HgO(s) ⟶ Hg(l) + O2(g)arrow_forwardPlease correct answer and don't use hand ratingarrow_forward
- 2) a)Determine AGX"° values for the following Combustion reactions at 25°C b) Decide whether this reaction is spontanious at 25°C or not CH:(g) + 02(g) CO:(g) + H;0 (1) AH (kJ/mol) s° (kJ/mol) CH4 -74.87 0.186 0.205 CO2 H,O -393.51 0.214 -285.83 0.070arrow_forwardCalculate the equilibrium constant at 25 °C for each of the following reactions from the value of ΔG° given.(a) I2(s) + Cl2(g) ⟶ 2ICl(g) ΔG° = −10.88 kJ(b) H2(g) + I2(s) ⟶ 2HI(g) ΔG° = 3.4 kJ(c) CS2(g) + 3Cl2(g) ⟶ CCl4(g) + S2 Cl2(g) ΔG° = −39 kJ(d) 2SO2(g) + O2(g) ⟶ 2SO3(g) ΔG° = −141.82 kJ(e) CS2(g) ⟶ CS2(l) ΔG° = −1.88 kJarrow_forwardGiven the following data, what is the value of ΔGf° (CH3OH(ℓ) at 25°C?CO(g) + 2 H2(g) ⇄ CH3OH(ℓ) K = 1.081 × 10-40ΔGf°(CO) = -137.2 kJ/molarrow_forward
- What is AS° at 298 K for the following reaction? CH4(g) + N2(g) → HCN(g) + NH3(g); AHº = 164.1 kJ; AG° = 159.1 kJ at 298 K ) a) 2.0 J/K O b) 1.1 × 10 J/K O c) 5.5 × 10² J/K. O d) 5.3 × 102 J/K () e) 17 J/Karrow_forwardCalculate T (in K) given ΔG^0= -19.4 kJ/mol and ΔH^0= 69.9 kJ/mol and ΔS^0= 253 J/mol KΔG^0=ΔH^0−TΔS^0 A) 706 B) 1,760 C) 353 D) 0.353 E) 118arrow_forwardHydrogen peroxide could react with methane gas at 298 K to yield methanol and water as the product in the reaction equation below. H2O2(g) + CH4(g) → CH3OH(g) + H2O(g) Calculate:(a) ∆S° (b) ∆H° (c) ∆G° (d) Kparrow_forward
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