
Interpretation:
The equilibrium constant for the reaction at temperature
Concept introduction:
The energy available with the system thatis utilized in doing useful work is called Gibbs free energy.
Entropy is the direct measurement of randomness or disorderness. Entropy is an extensive property. Entropy is a state function.
The enthalpy of a system is defined as the sum of the internal energy and the product of the pressure and the volume. Enthalpy is a state function and also an extensive property.
The solubility product of the sparingly soluble salt is given as the product of the concentrations of the ions raised to the power equal to the number of times the ion occurs in the equation after the dissociation of the electrolyte.

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Chapter 18 Solutions
Chemistry
- The following reaction is run in which the initial conditions include only methane (CH4) at a concentration of0.115 M. Once equilibrium was established, the concentration of acetylene (C2H2) was measured to be 0.035M. What is the value of the equilibrium constant, K?2 CH4 (g) ⇋ C2H2 (g) + 3 H2 (g)arrow_forwardCalculate the equilibrium concentration of carbon dioxide for the following reaction:2 COF2 (g) ⇋ CF4 (g) + CO2 (g) Kc = 2.00 at 10.00 °C. at equilibrium [COF2] = 0.255M; [CF4] = 0.118Marrow_forwardIn a benzene derivative that has -CH2CH3, indicate how it can be substituted by -COOH.arrow_forward
- In a sulfonated derivative of benzene, indicate how -SO3H can be eliminated.arrow_forwardWhat is the equilibrium expression (law of mass action) for the following reaction:CO2 (g) + H2O (l) ⇋ H+ (aq) + HCO3- (aq)arrow_forwardIndicate the compound resulting from adding NaOH cyclopentane-CH2-CHO.arrow_forward
- Use the provided information to calculate Kc for the following reaction at 550 °C: H2(g) + CO2(g) ⇌ CO(g) + H2O(g) Kc = ?CoO(s) + CO(g) ⇌ Co(s) + CO2(g) Kc1 = 490CoO(s) + H2(g) ⇌ Co(s) + H2O(g) Kc2 = 67arrow_forwardCalculate Kc for the reaction: I2 (g) ⇋ 2 I (g) Kp = 6.26 x 10-22 at 298Karrow_forwardFor each scenario below, select the color of the solution using the indicator thymol blue during the titration. When you first add indicator to your Na2CO3solution, the solution is basic (pH ~10), and the color is ["", "", "", "", ""] . At the equivalence point for the titration, the moles of added HCl are equal to the moles of Na2CO3. One drop (or less!) past this is called the endpoint. The added HCl begins to titrate the thymol blue indicator itself. At the endpoint, the indicator color is ["", "", "", "", ""] . When you weren't paying attention and added too much HCl (~12 mL extra), the color is ["", "", "", "", ""] . When you really weren't paying attention and reached the second equivalence point of Na2CO3, the color isarrow_forward
- To convert cyclopentane-CH2-CHO to cyclopentane-CH2-CH3, compound A is added, followed by (CH3)3CO-K+, DMS at 100oC. Indicate which compound A is.arrow_forwardIndicate how to obtain the compound 2-Hydroxy-2-phenylacetonitrile from phenylmethanol.arrow_forwardIndicate the reagent needed to go from cyclopentane-CH2-CHO to cyclopentane-CH2-CH=CH-C6H5.arrow_forward
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