The synthesis of the given compound from benzene has to be shown Concept Introduction: Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

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Answer 1

Question

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

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(a) 21.8 Name the following compounds. & (b) Br (e) O₂N. (h) H (c) Br (d) NH2 ☑N Br H ہیں Ph (g) OMe бл .0-0.e 21.9 Draw a structural formula for each compound. (a) 2,3-Dinitrotoluene (c) Diphenylmethanol (e) p-Nitroaniline (b) 3-Propylanisole (d) m-Propylphenol (f) Pentabromobenzene

Is this the major product of this reaction?

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Answer 2

Question

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

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Answer 3

Question

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

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Answer 4

Question

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

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Answer 5

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 6

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 7

Chapter 18.21, Problem 40P

a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 8

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 9

b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 10

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 11

c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 12

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 13

d)

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene has to be shown

Concept Introduction:

Aromatic compounds such as benzene which has closed ring and alternate double bonds undergo electrophilic aromatic substitution reactions. Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an aromatic ring. There are five most common electrophilic aromatic substitution reactions that are halogenation, nitration, sulfonation, Friedel-Crafts acylation and Friedel-Crafts alkylation. All these reactions take place by same two-step mechanism.

Answer 14

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Answer 16

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Answer 17

Ch. 18.1 - Draw the structure for each of the following: a....Ch. 18.3 - Why does hydration inactivate FeBr3?Ch. 18.6 - Prob. 4P Ch. 18.7 - What is the major product of a Friedel-Crafts...Ch. 18.9 - Describe two ways to prepare each of the following...Ch. 18.10 - Prob. 7P Ch. 18.11 - Name the following:Ch. 18.11 - Draw a structure for each of the following: a....Ch. 18.11 - Draw the structure for each of the following: a....Ch. 18.11 - Correct the following incorrect names: a....

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