Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 18.2, Problem 18.2P
Interpretation Introduction
Interpretation:
The equation for hydrolysis of GTP to GDP has to be written. Also, the sign of energy change has to be determined.
Concept Introduction:
1. Nitrogen-containing base
2. Pentose sugar
3. Phosphate group
Nitrogen-containing base and pentose sugar are collectively known as nucleoside. When a phosphate group is attached with nucleoside then it is termed as nucleotide. Examples of nucleosides are GTP and ATP. Nucleotide on hydrolysis releases energy by cleavage of phosphoanhydride bond.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The label on a can of ”Healthy Request” chicken noodle soup indicates that each 1-cup portion supplies 145 kcal and has 9 g of protein, 16 g of carbohydrate, and 5 g of fat.
Calculate the percentage of calories that come from protein, carbohydrates, and fat.
Use the following information corresponding to 1 Molar concentrations of reactants and products for Questions 7 -12.
Glycerol + ATP → ADP + 3-Phosphoglycerate:
ΔH = -63.39 kJ/mol and ΔS = -0.1255 kJ/molK.
Based on the information given above, Which of the following statements regarding this folding process are correct?
Use the following information corresponding to 1 Molar concentrations of reactants and products for Questions 7 -12.
Glycerol + ATP → ADP + 3-Phosphoglycerate:
ΔH = -63.39 kJ/mol and ΔS = -0.1255 kJ/molK.
Based on the information given above, Which of the following statements regarding this folding process are correct?
endothermic
exothermic
Enthapically driven
Entropically driven
Enthalpically opposed
Entropically opposed
at equilibrium
Exergonic for all temperatures
Endergonic for all temperatures
In glycolysis, the reaction of glucose (Glu) to form glucose-6-phosphate (G6P) requires ATP to be present as described by the
following equation: Glu+ ATP→G6) + ADP AG° = - 17KJ
In this process, ATP becomes ADP summarized by the following equation: ATP→ ADP A G° =- 30 kJ
What is the standard free energy change for the following reaction: Glu →G6P AG° =?
A 17 k)
B) -13 k)
c) 13 kJ
-17 kJ
Chapter 18 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 18.1 - Prob. 18.1PCh. 18.2 - Prob. 18.2PCh. 18.2 - Prob. 18.3PCh. 18.2 - Prob. 18.4PCh. 18.3 - Prob. 18.5PCh. 18.3 - What makes riboflavin a water-soluble vitamin?Ch. 18.3 - Prob. 18.7PCh. 18.4 - Identify the type of carbonyl groups present in...Ch. 18.4 - Prob. 18.9PCh. 18.4 - Prob. 18.10P
Ch. 18.5 - Prob. 18.11PCh. 18.5 - (a) In what way(s) is the conversion of pyruvate...Ch. 18.6 - Prob. 18.15PCh. 18 - Prob. 18.31UKCCh. 18 - Prob. 18.32UKCCh. 18 - When a substrate is oxidized, is NAD+ oxidized or...Ch. 18 - When a substrate is reduced, is FADH2 oxidized or...Ch. 18 - Prob. 18.35UKCCh. 18 - Prob. 18.36UKCCh. 18 - Prob. 18.39UKCCh. 18 - Prob. 18.40UKCCh. 18 - Prob. 18.41UKCCh. 18 - Prob. 18.42UKCCh. 18 - Prob. 18.45APCh. 18 - What is the difference between metabolism and...Ch. 18 - Prob. 18.47APCh. 18 - Prob. 18.48APCh. 18 - Prob. 18.49APCh. 18 - Prob. 18.50APCh. 18 - Prob. 18.51APCh. 18 - Prob. 18.52APCh. 18 - Prob. 18.53APCh. 18 - Classify each substance as an oxidizing agent, a...Ch. 18 - Prob. 18.55APCh. 18 - Prob. 18.56APCh. 18 - Prob. 18.58APCh. 18 - What is the role of each of the following in the...Ch. 18 - Prob. 18.71APCh. 18 - Prob. 18.72AP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The first step of the metabolic process known as glycolysis is the conversion of glucose to glucose- 6-phosphate. This process has a positive value for rG' Glucose + Pi Glucose-6-phosphate + H2O rG' = +13.8 kJ/mol-rxn This reaction is coupled to the hydrolysis of ATP ATP + H2O ADP + Pi rG' = -30.5 kJ/mol-rxn What is the sum of these two equations and the value of rG' for the coupled reaction? Is the coupled reaction product-favored at equilibrium?arrow_forwarda 75 kg adult requires a calorie intake of 2000 Cal of food every 24 hours. The food is metabolized, and the free energy is used to synthesis ATP for useful work. {each Calorie listed on food labels corresponds to 1.0 Cal in biochemical terms}. Assuming that the efficiency of converting food energy into ATP is 50%. Calculate the weight of ATP used by this human in 24 hours and the percentage of the person’s body weight that this represents. {the formula mass of ATP is 505 g/mol and each mole of ATP is equivalence to 7.30 Cal}arrow_forwardCalculate the equilibrium constant for the following reaction at 37 oC. Fructose 1,6-bisphosphate + ADP → Fructose 6-phosphate + ATP ΔGo’ = 14.27 kJ/molarrow_forward
- Consider the coupled reactions: kcal AGO'= -16.3 mol 1,3-ВPG 3-PG + Pi AG°'= -7.3 kcal mol ATP → ADP + P; What is the net reaction? 3-PG + ADP + Pi→ 1,3-BPG + ATP 3-PG + ATP → 1,3-BPG + ADP + P¡ O 1,3-BPG + ADP + P¡ –→ 3-PG + ATP O 1,3-BPG + ATP → 3-PG + ADP + P¡arrow_forwardPlease calculate the missing energy to complete the complete Born-Haber cycle.(please give the negative sign "-" if your answer is negative; if your answer is positive, do not put the positive sign "+") calculate the missing energy to complete the complete born-haber cycle (please indicate whether negative or positive) *energie de cohesion du réseau ionique = ionic network cohesion energy *réaction global = global reaction (please give the missing réaction if it's possible :) with the charges)arrow_forwardOne gram of alcohol provides 7 Calories. Calculate the number of Calories in a 5 fluid ozoz glass of red wine that contains 3.0 gg carbohydrate and 12.1 gg alcohol.arrow_forward
- Actual free-energy change is a function of the reactant and product concentrations and the temperature at which the reaction occurs. AG = Go + RT In Use the equation for the actual free-energy change to plot AG against In Q at 25 °C for the five concentrations of ATP, ADP, and P₁ shown in the table. The AG' for the reaction is -30.5 kJ/mol. Concentration (mm) 0.2 5.0 14.9 O O AG (kJ/mol) Metabolite ATP ADP P₁ Select the graph that plots the data. AG (kJ/mol) 0 -20 -40 -~ 0 200 0 -200 [C]c[D]d [A]a[B]b -400 T 2 5 0.2 10 2 T 4 3 2.2 12.1 InQ 6 4 InQ 6 8 1 4.2 14.1 10 8 5 25 10 AG (kJ/mol) AG (kJ/mol) 0 -20 -40 -10 -8 0 -20 -40 -6 -4 InQ -2 0arrow_forwardGiven that the reaction of 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 3 H2O (g) ΔΗ - 906 kJ What would AH for NO (g) + 3 H2O (g) → NH3 (g) + O2 (g) be? O 226.5 kJ O 453 kJ -226.5 kJ O 906 kJarrow_forwardIn the system: C(s) + O2(g) + 2HCI(g) – COCI2(g) + H20(g) + heat how is it possible to increase the amount of heat evolved? add some carbon add a catalyst remove some of the HCI add COCI2 Add some O2arrow_forward
- Answer the following questions about the fermentation of glucose (C6H12O6, molar mass 180.2 g/mol) to ethanol (C2H6O) and CO2. C6H12O6(s) → 2 C2H6O(l) + 2 CO2(g) ΔH = −16 kcal/mol glucose ethanol How many kilocalories of energy are released when 6.9 mol of ethanol is formed? kcal of energy released Report answer to appropriate number of significant figures.arrow_forwardIn the following reactions, identify the substance oxidized, the substance reduced, the oxidizing agent, & the reducing agent. ronmenta Malate Oxaloacetate Руruvate Lactate COO- COO- || C-o- C-0- Но -С—Н C=0 (a) | ċ=0 (b) Но-С—Н CH2 CH, ČOO- ČOO- Pyruvate + NADH + H' → Lactate + NAD* Malate + NAD* –Oxaloacetate + NADH + H* (1) (2)arrow_forwardHi, Please help me answer these two questions. Hope I'd get all the items done. PS. If possible, provide explanations on it. Thank you so much. *** 1. Calculate the value of ΔGo’ for the following reaction. Glucose-1-phosphate → Glucose-6-phosphate Given: Glucose-1-phosphate → Glucose + Pi ΔGo’ = -20.9 kJ/mol Glucose + Pi → Glucose-6-phosphate ΔGo’ = +12.5 kJ/mol 2. The ΔGo’ for Coupled Reactions. Glucose-1-phosphate is converted into fructose-6-phosphate in two successive reactions: Glucose 1-phosphate →glucose 6-phosphate ΔGo’ = -7.3 kJ/mol Glucose 6-phosphate→fructose 6-phosphate ΔGo’ = + 1.7 kJ/mol Calculate the overall ΔGo’ and the equilibrium constant, K’eq for the sum of the two reactions: Glucose 1-phosphate → fructose 6-phosphatearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry In FocusChemistryISBN:9781305084476Author:Tro, Nivaldo J., Neu, Don.Publisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry In Focus
Chemistry
ISBN:9781305084476
Author:Tro, Nivaldo J., Neu, Don.
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning