Principles of General, Organic, Biological Chemistry
Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 18, Problem 18.51AP

(a)

Interpretation Introduction

Interpretation:

Chemical equation for conversion of fructose1,6-biphosphate to fructose6-phosphate has to be written.

Concept Introduction:

Nucleotide is defined as basic unit for formation of nucleic acid that is essential for completion of metabolic reactions in body. The three basic components of nucleotide are as follows:

1. Nitrogen-containing base

2. Pentose sugar

3. Phosphate group

Examples of nucleosides are GTP and ATP. Nucleotide on hydrolysis releases energy by cleavage of phosphoanhydride bond. The reaction of hydrolysis of ATP is as follows:

  ATP+H2OADP+Pi+energy

(b)

Interpretation Introduction

Interpretation:

Whether energy is released or absorbed in formation of fructose6-phosphate by fructose1,6-biphosphate has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Whether reaction is energetically favorable or not in formation of fructose6-phosphate by fructose1,6-biphosphate has to be determined.

Concept Introduction:

Refer to part (a).

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The oxidation of 1 mol of glucose supplies enough meta-bolic energy to form 36 mol of ATP. Oxidation of 1 mol of a typ-ical dietary fat like tristearin (C₅₇H₁₁₆O₆) yields enough energyto form 458 mol of ATP. (a) How many molecules of ATP canform per gram of glucose? (b) Per gram of tristearin?
All are true of the Embden-Myerhof pathway EXCEPT     Question 88 options:   A)  the products pyruvic acid and ATP under aerobic conditions enter the Krebb's (TCA) cycle to produce more ATP   B)  the products pyruvic acid and ATP under anaerobic conditions are converted to lactic acid and two additional ATP   C)  Cells use this pathway when they have no energy needs   D)  Begins with the conversion of glucose into glucose-6-phosphate
From what you learned about monosaccharides in Chapter 20and phosphates in Chapter 23 : (a) Draw the structure of glucose 6-phosphate. (b) Using structures, write the equation for the hydrolysis of glucose 6-phosphate to glucose and HPO 42−.
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