The product of the given reaction has to be predicted. Concept introduction: The reaction between ketone / aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

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Answer 5

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

Answer 6

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 7

Chapter 18.15, Problem 18.22P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get desired product (an imine).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 18.3 - Give the IUPAC name and (if possible) a common...Ch. 18.5D - NMR spectra for two compounds are given here,...Ch. 18.5D - Why were no products from the McLafferty...Ch. 18.5D - Use equations to show the fragmentation leading to...Ch. 18.5E - Prob. 18.5P Ch. 18.7D - Show how you would synthesize each compound from...Ch. 18.8 - Prob. 18.7P Ch. 18.9 - Predict the products of the following reactions....Ch. 18.9 - Show how the following transformations may be...Ch. 18.10 - Prob. 18.10P

Solution Summary: The author explains that the reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps.

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Chapter 18 Solutions