(a) Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any. Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C = C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide , like CH 3 X or RCH 2 X .

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Question

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

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4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).

Answer 2

Question

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

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Answer 3

Question

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

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Answer 4

Question

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

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Answer 5

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 6

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 7

Chapter 18, Problem 54P

Interpretation Introduction

(a)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 8

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 9

Interpretation Introduction

(b)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 10

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 11

Interpretation Introduction

(c)

Interpretation: The Wittig reagent and carbonyl compound that are needed to prepare the given alkene are to be predicted, and the preferred route is to be identified, if any.

Concept introduction: One should follow the two steps retrosynthesis to find out the starting materials that are needed to prepare the given alkene. The first step is cleaving of C=C into two components, carbonyl and Wittig reagent. The second step is selection of preferred pathway. While selection one should consider that pathway in which Wittig reagent is derived from an unhindered alkyl halide, like CH3X or RCH2X.

Answer 12

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Answer 15

Ch. 18.1 - Rank the following compounds in order of...Ch. 18.1 - Prob. 2P Ch. 18.2 - Give the IUPAC name for each aldehyde.Ch. 18.2 - Prob. 4P Ch. 18.2 - Give the IUPAC name for each ketone.Ch. 18.5 - Prob. 11P Ch. 18.9 - Problem 21.17 Draw the products of the following...Ch. 18.9 - Problem 21.18 Outline a synthesis of each Wittig...Ch. 18.9 - Problem 21.19 Draw the products (including...Ch. 18.9 - Problem 21.20 What starting materials are needed...

Solution Summary: The author explains the two steps retrosynthesis to find out the Wittig reagent and carbonyl compound that are needed to prepare the given alkene.

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Chapter 18 Solutions