ORGANIC CHEMISTRY W/ALEKS
6th Edition
ISBN: 9781264905430
Author: SMITH
Publisher: MCG CUSTOM
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Question
Chapter 18.10, Problem 21P
Interpretation Introduction
(a)
Interpretation: The starting material required for the preparation of given imine is to be determined.
Concept introduction:
Interpretation Introduction
(b)
Interpretation: The starting material required for the preparation of given imine is to be determined.
Concept introduction: Aldehyde or ketone on reaction with primary amine forms imine. Imine is also known as Schiff base. The nucleophilic attack of primary amine on carbonyl carbon results in the formation of intermediate carbinolamine. This intermediate loses water to form an imine.
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If I have 30% H2O2, indicate how to prepare a 6% H2O2 solution.
7)
8)
FCI II
-C-C-C=C-C
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Br Br
||
-C=C-Br
-CEC-C-C-
10)
11)
F Br
i
OH
مله
12)
Br
i
13)
14)
15)
CH3CHFCHFC=CH
C(OH)Br2CHF(CH2)4CH2CH3
CH3(CH2)3CH=CH(CH2)2CH3
Name
1) 3-fluoro, 1-butene
2) 2-heptene
2,3-difluoro-
1-pentene
4) 6-iodo,4-methyl-
2-decyne
5) 4,4-dibromo-
1,2-butandiol
Complete structural formula
F
-C=C-C-C-
Line formula
Condensed structural formula
N
F
CH2=CHCHFCH3
Chapter 18 Solutions
ORGANIC CHEMISTRY W/ALEKS
Ch. 18.1 - Rank the following compounds in order of...Ch. 18.1 - Prob. 2PCh. 18.2 - Give the IUPAC name for each aldehyde.Ch. 18.2 - Prob. 4PCh. 18.2 - Give the IUPAC name for each ketone.Ch. 18.5 - Prob. 11PCh. 18.9 - Problem 21.17 Draw the products of the following...Ch. 18.9 - Problem 21.18 Outline a synthesis of each Wittig...Ch. 18.9 - Problem 21.19 Draw the products (including...Ch. 18.9 - Problem 21.20 What starting materials are needed...
Ch. 18.9 - Prob. 19PCh. 18.10 - Problem 21.22 The product formed when reacts with...Ch. 18.10 - Prob. 21PCh. 18.11 - Prob. 22PCh. 18.11 - Prob. 23PCh. 18.11 - Prob. 24PCh. 18.12 - Prob. 25PCh. 18.12 - Problem 21.28 Draw a stepwise mechanism for the...Ch. 18.13 - Problem 21.29 Draw the products of each...Ch. 18 - Problem 21.40 (a) Give the IUPAC name for A and B....Ch. 18 - 21.41 Rank the following compounds in order of...Ch. 18 - Prob. 39PCh. 18 - 21.43 Give the IUPAC name for each compound.
a....Ch. 18 - 21.44 Give the structure corresponding to each...Ch. 18 - Prob. 42PCh. 18 - 21.46 Draw the products of each reaction.
a. e....Ch. 18 - Prob. 44PCh. 18 - 21.48 Draw all stereoisomers formed in each...Ch. 18 - Prob. 54PCh. 18 - Prob. 55PCh. 18 - Prob. 56PCh. 18 - Devise a synthesis of each alkene using a Wittig...Ch. 18 - Prob. 60PCh. 18 - Prob. 62PCh. 18 - Prob. 63PCh. 18 - 21.64 Draw a stepwise mechanism for the following...Ch. 18 - 21.65 Draw a stepwise mechanism f or the following...Ch. 18 - Prob. 67PCh. 18 - 21.67 Draw a stepwise mechanism for each...Ch. 18 - Prob. 69PCh. 18 - Prob. 70P
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