EBK CHEMICAL PRINCIPLES
EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 9781305856745
Author: DECOSTE
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 18, Problem 47E

(a)

Interpretation Introduction

Interpretation: The reason of dimerization of nitrogen dioxide to form dinitrogen tetroxide on the basis of Lewis structure needs to be determined.

Concept Introduction:

Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that exist on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.

The sum of valence electrons must be arranged in such a way that all atoms must get octet configuration (8 electrons). The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell is represented as lone pair of electrons.

(b)

Interpretation Introduction

Interpretation: The reason of acceptance of boron trihydride accepts a pair of electrons from ammonia to for BH3NH3 needs to be explained.

Concept Introduction:

Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.

The sum of valence electrons must be arranged in such a way that all atoms must get octet configuration (8 electrons). The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell is represented as lone pair of electrons.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

Chapter 18 Solutions

EBK CHEMICAL PRINCIPLES

Ch. 18 - Prob. 11ECh. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - Prob. 16ECh. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - Prob. 23ECh. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Prob. 43ECh. 18 - Prob. 44ECh. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - Prob. 47ECh. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - The synthesis of ammonia gas from nitrogen gas...Ch. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Prob. 63ECh. 18 - Prob. 64ECh. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Prob. 67ECh. 18 - Prob. 68ECh. 18 - Prob. 69ECh. 18 - Prob. 70ECh. 18 - Prob. 71ECh. 18 - Prob. 72ECh. 18 - Prob. 73ECh. 18 - Prob. 74ECh. 18 - Prob. 75ECh. 18 - Prob. 76ECh. 18 - Prob. 77ECh. 18 - Prob. 78ECh. 18 - Prob. 79ECh. 18 - Prob. 80ECh. 18 - Prob. 81ECh. 18 - Prob. 82ECh. 18 - Prob. 83ECh. 18 - Prob. 84ECh. 18 - Prob. 85ECh. 18 - Prob. 86ECh. 18 - Prob. 87ECh. 18 - Prob. 88ECh. 18 - Prob. 89ECh. 18 - Prob. 90AECh. 18 - Prob. 91AECh. 18 - Prob. 92AECh. 18 - Prob. 93AECh. 18 - Prob. 94AECh. 18 - Prob. 95AECh. 18 - Prob. 96AECh. 18 - Prob. 97AECh. 18 - Prob. 98AECh. 18 - Prob. 99AECh. 18 - Prob. 100AECh. 18 - Prob. 101AECh. 18 - Prob. 102AECh. 18 - Prob. 103AECh. 18 - Prob. 104AECh. 18 - Prob. 105AECh. 18 - Prob. 106AECh. 18 - Prob. 107AECh. 18 - Prob. 108AECh. 18 - Prob. 109AECh. 18 - Prob. 110AECh. 18 - Prob. 111AECh. 18 - Prob. 112AECh. 18 - Hydrogen gas is being considered as a fuel for...Ch. 18 - Prob. 114AECh. 18 - Prob. 115AECh. 18 - Prob. 116AECh. 18 - Prob. 117AECh. 18 - Prob. 118AECh. 18 - Prob. 119AECh. 18 - What is the molecular structure for each of the...Ch. 18 - Prob. 121AECh. 18 - Prob. 122AECh. 18 - Prob. 123CPCh. 18 - Prob. 124CPCh. 18 - Prob. 125CPCh. 18 - Prob. 126CPCh. 18 - Prob. 127CPCh. 18 - Prob. 128CPCh. 18 - Prob. 129CPCh. 18 - Prob. 130CPCh. 18 - Prob. 131CPCh. 18 - Prob. 132CPCh. 18 - Prob. 133CP
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