EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
bartleby

Concept explainers

Question
Book Icon
Chapter 18, Problem 45P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

  • The groups present on first and second position on benzene ring are said to be at ortho position.
  • The groups present on first and third position on benzene ring are said to be at meta position.
  • The groups present on first and fourth position on benzene ring are said to be at pera position.

Blurred answer
Students have asked these similar questions
81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE
Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Chapter 18 Solutions

EBK ORGANIC CHEMISTRY

Ch. 18.12 - Prob. 14PCh. 18.12 - List the compounds in each set from most reactive...Ch. 18.13 - Prob. 16PCh. 18.13 - What product(s) result from nitration of each of...Ch. 18.13 - Prob. 18PCh. 18.13 - What products are obtained from the reaction of...Ch. 18.15 - Give the products, if any, of each of the...Ch. 18.16 - a. Does a coupling reaction have to be used to...Ch. 18.16 - Show how the following compounds can be...Ch. 18.16 - Prob. 24PCh. 18.17 - What is the major product(s) of each of the...Ch. 18.17 - Prob. 26PCh. 18.18 - Why isn't FeBr3 used as a catalyst in the first...Ch. 18.18 - Prob. 29PCh. 18.18 - Write the sequence of steps required for the...Ch. 18.18 - Show how the following compounds can be...Ch. 18.19 - What product is formed from reaction of...Ch. 18.19 - Prob. 33PCh. 18.19 - Draw the structure of the activated ring and the...Ch. 18.20 - Prob. 35PCh. 18.20 - Prob. 36PCh. 18.20 - Diazomethane can be used to convert a carboxylic...Ch. 18.21 - Prob. 38PCh. 18.21 - Prob. 39PCh. 18.21 - Prob. 40PCh. 18.22 - Prob. 41PCh. 18 - Draw the structure for each of the following: a....Ch. 18 - Name the following:Ch. 18 - Prob. 44PCh. 18 - Prob. 45PCh. 18 - For each of the statements in Column I, choose a...Ch. 18 - What product is obtained from the reaction of...Ch. 18 - Draw the product(s) of each of the following...Ch. 18 - Rank the following substituted anilines from most...Ch. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Show how the following compounds can be...Ch. 18 - Prob. 53PCh. 18 - The compound with the 1H NMR spectrum shown below...Ch. 18 - Rank each group of compounds from most reactive to...Ch. 18 - Prob. 56PCh. 18 - Prob. 57PCh. 18 - For each of the following components, indicate the...Ch. 18 - Prob. 59PCh. 18 - Prob. 60PCh. 18 - Describe two ways to prepare anisole from benzene.Ch. 18 - Prob. 62PCh. 18 - The following tertiary alkyl bromides undergo an...Ch. 18 - An aromatic hydrocarbon with a molecular formula...Ch. 18 - Show how the following compounds can be...Ch. 18 - Use the four compounds shown below to answer the...Ch. 18 - a. Rank the following esters from most reactive to...Ch. 18 - A mixture of 0.10 mol benzene and 0.10 mol...Ch. 18 - Prob. 69PCh. 18 - Prob. 70PCh. 18 - Benzene underwent a Friedel-Crafts acylation...Ch. 18 - Prob. 72PCh. 18 - Prob. 73PCh. 18 - Friedel-Crafts alkylations can be carried out with...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - Prob. 76PCh. 18 - Prob. 77PCh. 18 - a. Describe four ways the following reaction can...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - How can you prepare the following compounds with...Ch. 18 - Describe how naphthalene can he prepared from the...Ch. 18 - Using resonance contributors for the carbocation...Ch. 18 - Prob. 83PCh. 18 - What reagents are required to carry out the...Ch. 18 - Prob. 85PCh. 18 - Prob. 86PCh. 18 - Prob. 87PCh. 18 - Propose a mechanism for each of the following...Ch. 18 - P-Fluoronitrobenzene is more reactive toward...Ch. 18 - When heated with chromic acid, compound A forms...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - How can you distinguish the following compounds...Ch. 18 - Describe how mescaline can be synthesized from...Ch. 18 - Propose a mechanism for the following reaction...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - Describe how 3-methyl-1-phenyl-3-pentanol can he...Ch. 18 - An unknown compound reacts with ethyl chloride and...Ch. 18 - a. Explain why the following reaction leads to the...Ch. 18 - Explain why hydroxide ion catalyzes the reaction...Ch. 18 - Prob. 100PCh. 18 - Prob. 101PCh. 18 - a. How can aspirin be synthesized from benzene? b....Ch. 18 - Prob. 103PCh. 18 - Show how Novocain, a painkiller used frequently by...Ch. 18 - Prob. 105PCh. 18 - Saccharin, an artificial sweetener, is about 300...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY