Connect  One Semester Access Card for General, Organic, & Biological Chemistry
Connect One Semester Access Card for General, Organic, & Biological Chemistry
4th Edition
ISBN: 9781260194654
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
Question
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Chapter 18, Problem 29P
Interpretation Introduction

(a)

Interpretation:

From the given compounds from A to D, a compound containing a primary amine and a primary alcohol needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 .Amines are classified as 10,20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond

  20 amines- Consist two CN bond

  30 amines- Consist three CN bond

Alcohol- is an organic compound contains the group of OH , bonded to a tetrahedral C atom.Alcohols are classified as 10,20 or 30 by the number of C atoms bonded to the C with the OH group.

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

Expert Solution
Check Mark

Answer to Problem 29P

Structure C.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines - Consist two CN bond.

  30 amines - Consist three CN bond.

Furthermore,

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

In the below stick and ball structure, C atoms are representing in black color, H atoms in white color, N atoms in blue color and O atoms in red color. Stick and ball structure can be simplified as below;

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  1

Bond that is indicated in red color is the only one CC bond that connects to the OH group boned C in alcohol which makes it as an 10 alcohol. Bond that is indicated in blue color is the single CN bond in the amine group which is responsible for the 10 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  2

Hence, structure C is a compound that contains a 10 amine and a 10 alcohol.

Interpretation Introduction

(b)

Interpretation:

From the given compounds from A to D, a compound containing a secondary amine and a secondary alcohol needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 .Amines are classified as 10,20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond

  20 amines- Consist two CN bonds

  30 amines- Consist three CN bonds

Alcohol- is an organic compound contains the group of OH , bonded to a tetrahedral C atom. Alcohols are classified as 10,20 or 30 by the number of C atoms bonded to the C with the OH group.

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

Expert Solution
Check Mark

Answer to Problem 29P

Structure D.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines - Consist two CN bonds.

  30 amines - Consist three CN bonds.

Furthermore,

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

In the below stick and ball structure, C atoms are representing in black color, H atoms in white color, N atoms in blue color and O atoms in red color. Stick and ball structure can be simplified as below;

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  3

Bonds that are indicated in red color are the two CC bonds that connects to the OH group boned C in alcohol which makes it as an 20 alcohol. Bonds that are indicated in blue color are the two CN bonds in the amine group which is responsible for the 20 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  4

Hence, structure D is a compound that contains a 20 amine and a 20 alcohol.

Interpretation Introduction

(c)

Interpretation:

From the given compounds from A to D, a compound containing a primary amine and a tertiary alcohol needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 .Amines are classified as 10,20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond

  20 amines- Consist two CN bond

  30 amines- Consist three CN bond

Alcohol- is an organic compound contains the group of OH , bonded to a tetrahedral C atom. Alcohols are classified as 10,20 or 30 by the number of C atoms bonded to the C with the OH group.

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

Expert Solution
Check Mark

Answer to Problem 29P

Structure B.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines - Consist two CN bonds.

  30 amines - Consist three CN bonds.

Furthermore,

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

In the below stick and ball structure, C atoms are representing in black color, H atoms in white color, N atoms in blue color and O atoms in red color. Stick and ball structure can be simplified as below;

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  5

Bonds that are indicated in red color are the three CC bonds that connects to the OH group boned C in alcohol which makes it as an 30 alcohol. Bond that is indicated in blue color is the CN bondin the amine group which is responsible for the 10 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  6

Hence, structure B is a compound that contains a 10 amine and a 30 alcohol.

Interpretation Introduction

(d)

Interpretation:

From the given compounds from A to D, a compound containing a tertiary amine and a primary alcohol needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 .Amines are classified as 10,20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond

  20 amines- Consist two CN bonds

  30 amines- Consist three CN bonds

Alcohol- is an organic compound contains the group of OH , bonded to a tetrahedral C atom. Alcohols are classified as 10,20 or 30 by the number of C atoms bonded to the C with the OH group.

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

Expert Solution
Check Mark

Answer to Problem 29P

Structure A.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines - Consist two CN bond.

  30 amines - Consist three CN bond.

Furthermore,

  10 alcohols - Consist an OH group on a carbon bonded to one carbon.

  20 alcohols - Consist an OH group on a carbon bonded to two carbons.

  30 alcohols - Consist an OH group on a carbon bonded to two carbons.

In the below stick and ball structure, C atoms are representing in black color, H atoms in white color, N atoms in blue color and O atoms in red color. Stick and ball structure can be simplified as below;

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  7

Bond that is indicated in red color is the only one CC bonds that connects to the OH group boned C in alcohol which makes it as an 10 alcohol. Bonds that are indicated in blue color are the three CN bonds in the amine group which is responsible for the 30 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 29P , additional homework tip  8

Hence, structure A is a compound that contains a 30 amine and a 10 alcohol.

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Chapter 18 Solutions

Connect One Semester Access Card for General, Organic, & Biological Chemistry

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