
Concept explainers
(a)
Interpretation:
The balanced equation for the following nuclear reaction should be written.
The bombardment of Fe-54 with alpha particle results in the production of another nucleus with two protons.
Concept introduction:
A reaction in which a nucleus of an atom or two nuclei and a subatomic particle collide to form one or more nuclide which is different from the starting nuclide is known as nuclear reaction. Nuclear reactions can be classified as nuclear fission and nuclear fusion.

Answer to Problem 18QAP
Explanation of Solution
The reaction in which the change in
Given that, the bombardment of Fe-54 with alpha particle results in the production of another nucleus with two protons.
Fe-54 is the isotope of iron, atomic number of iron is 26.
To identify the missing species: Let the species be
The reaction can be written as:
To balance the reaction: Mass number of the reactant must be equal to the mass number of the product.
Now, atomic number or charges must be balanced, therefore:
Thus, the product must have mass number and atomic number equal to 56 and 26. From the periodic table, the nucleus is
Overall reaction is:
(b)
Interpretation:
The balanced equation for the following nuclear reaction should be written.
The bombardment of Mo-96 with
Concept introduction:
A reaction in which a nucleus of an atom or two nuclei and a subatomic particle collide to form one or more nuclide which is different from the starting nuclide is known as nuclear reaction. Nuclear reactions can be classified as nuclear fission and nuclear fusion.

Answer to Problem 18QAP
Explanation of Solution
The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes place is known as nuclear reaction.
Given that, the bombardment of Mo-96 with
Mo-96 is the isotope of molybdenum, atomic number of molybdenum is 42.
Now, symbol of neutron is
To identify the missing species: Let the species be
The reaction can be written as:
To balance the reaction: Mass number of the reactant must be equal to the mass number of the product.
Now, atomic number or charges must be balanced, therefore:
Thus, the product must have mass number and atomic number equal to 97 and 43. From the periodic table, the nucleus is
Overall reaction is:
(c)
Interpretation:
The balanced equation for the following nuclear reaction should be written.
The bombardment of Ar-40 with an unknown particle in the production of K-43 with a proton.
Concept introduction:
A reaction in which a nucleus of an atom or two nuclei and a subatomic particle collide to form one or more nuclide which is different from the starting nuclide is known as nuclear reaction. Nuclear reactions can be classified as nuclear fission and nuclear fusion.

Answer to Problem 18QAP
Explanation of Solution
The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes place is known as nuclear reaction.
Given that, the bombardment of Ar-40 with an unknown particle in the production of K-43 with a proton.
Ar-40 is the isotope of argon atomic number of argon is 18.
K-43 is the isotope of potassium, atomic number of potassium is 19.
To identify the missing species: Let the species be
The reaction can be written as:
To balance the reaction: Mass number of the reactant must be equal to the mass number of the product.
Now, atomic number or charges must be balanced, therefore:
Thus, the reactant must have mass number and atomic number equal to 4 and 2. From the periodic table, the nucleus is
Overall reaction is:
(d)
Interpretation:
The balanced equation for the following nuclear reaction should be written.
The bombardment of nucleus with a neutron results in the production of a proton with P-31.
Concept introduction:
A reaction in which a nucleus of an atom or two nuclei and a subatomic particle collide to form one or more nuclide which is different from the starting nuclide is known as nuclear reaction. Nuclear reactions can be classified as nuclear fission and nuclear fusion.

Answer to Problem 18QAP
Explanation of Solution
The reaction in which the change in atomic numbers, energy states and mass number of nuclei takes place is known as nuclear reaction.
Given that, the bombardment of nucleus with a neutron results in the production of a proton with P-31.
P-31 is the isotope of phosphorus, atomic number of phosphorus is 15.
To identify the missing species: Let the species be
The reaction can be written as:
To balance the reaction: Mass number of the reactant must be equal to the mass number of the product.
Now, atomic number or charges must be balanced, therefore:
Thus, the product must have mass number and atomic number equal to 13 and 16. From the periodic table, the nucleus is
Overall reaction is:
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Chapter 18 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
- Propose a synthesis of 1-butanamine from the following: (a) a chloroalkane of three carbons (b) a chloroalkane of four carbonsarrow_forwardSelect the stronger base from each pair of compounds. (a) H₂CNH₂ or EtzN (b) CI or NH2 NH2 (c) .Q or EtzN (d) or (e) N or (f) H or Harrow_forward4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HOarrow_forward
- b. H3C CH3 H3O+ ✓ H OHarrow_forward2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3arrow_forwardIdentify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.arrow_forward
- Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.arrow_forwardInstructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.arrow_forwardе. Д CH3 D*, D20arrow_forward
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