Use the data in Appendix B to calculate Δ H o and Δ S o for each of the following reactions. From the values of Δ H o and Δ S o , calculate Δ G o at 25 °C, and predict whether each reaction is spontaneous under standard-state conditions. (a) N 2 ( g ) + 2 O 2 ( g ) → 2 NO 2 ( g ) (b) CH 3 CH 2 OH(l)+O 2 ( g ) → CH3CO2H(l)+H 2 O(l)
Use the data in Appendix B to calculate Δ H o and Δ S o for each of the following reactions. From the values of Δ H o and Δ S o , calculate Δ G o at 25 °C, and predict whether each reaction is spontaneous under standard-state conditions. (a) N 2 ( g ) + 2 O 2 ( g ) → 2 NO 2 ( g ) (b) CH 3 CH 2 OH(l)+O 2 ( g ) → CH3CO2H(l)+H 2 O(l)
Solution Summary: The author explains that the second law of thermodynamics gives criteria for spontaneity. When sign of total entropy change is positive, the reaction is spontaneous.
Use the data in Appendix B to calculate
Δ
H
o
and
Δ
S
o
for each of the following reactions. From the values of
Δ
H
o
and
Δ
S
o
, calculate
Δ
G
o
at 25 °C, and predict whether each reaction is spontaneous under standard-state conditions. (a)
N
2
(
g
)
+ 2 O
2
(
g
)
→
2 NO
2
(
g
)
(b)
CH
3
CH
2
OH(l)+O
2
(
g
)
→
CH3CO2H(l)+H
2
O(l)
Transmitance
3. Which one of the following compounds corresponds to
this IR spectrum?
Point out the absorption band(s) that helped you
decide.
OH
H3C
OH
H₂C
CH3
H3C
CH3
H3C
INFRARED SPECTRUM
0.8-
0.6
0.4-
0.2
3000
2000
1000
Wavenumber (cm-1)
4. Consider this compound:
H3C
On the structure above, label the different types of H's
as A, B, C, etc.
In table form, list the labeled signals, and for each
one state the number of hydrogens, their shifts, and the
splitting you would observe for these hydrogens in the ¹H
NMR spectrum.
Label
# of hydrogens
splitting
Shift (2)
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY