Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Textbook Question
Chapter 18, Problem 18.82E
The basic structure of cell membrane is a:
a. protein bilayer.
b. protein-impregnated phospholipid bilayer.
c. carbohydrate bilayer.
d. phospholipid bilayer.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
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The following liquid-liquid extraction is different from the one you performed in Experiment
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A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 18 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 18 - What is the basis for deciding if a substance is a...Ch. 18 - List two major functions of lipids in the human...Ch. 18 - What functional group is common to all...Ch. 18 - Prob. 18.4ECh. 18 - Prob. 18.5ECh. 18 - Describe four structural characteristics exhibited...Ch. 18 - Describe the structure of a micelle formed by the...Ch. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Explain why the melting points of unsaturated...
Ch. 18 - What structural feature of a fatty acid is...Ch. 18 - How are fats and oils structurally similar? How...Ch. 18 - From Figure 18.7, arrange the following substances...Ch. 18 - Draw the structure of a triglyceride that contains...Ch. 18 - Prob. 18.15ECh. 18 - The percentage of fatty acid composition of two...Ch. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Why is the hydrogenation of vegetable oils of...Ch. 18 - Prob. 18.21ECh. 18 - Write reactions to show how each of the following...Ch. 18 - Draw the structure of a wax formed from oleic acid...Ch. 18 - Prob. 18.24ECh. 18 - Draw the structure of a wax formed from stearic...Ch. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Draw the general block diagram structure of a...Ch. 18 - Draw the structure of a phosphoglyceride...Ch. 18 - Describe two biological roles served by the...Ch. 18 - Prob. 18.31ECh. 18 - What is the structural difference between a...Ch. 18 - Prob. 18.33ECh. 18 - Prob. 18.34ECh. 18 - List two structural differences between...Ch. 18 - Prob. 18.36ECh. 18 - Describe the structural similarities and...Ch. 18 - Give another name for glycolipids. In what tissues...Ch. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - How does the polarity of the phosphoglycerides...Ch. 18 - Prob. 18.42ECh. 18 - Prob. 18.43ECh. 18 - Prob. 18.44ECh. 18 - Explain how bile salts aid in the digestion of...Ch. 18 - Prob. 18.46ECh. 18 - Prob. 18.47ECh. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Prob. 18.50ECh. 18 - How are testosterone and progesterone structurally...Ch. 18 - Prob. 18.52ECh. 18 - Prob. 18.53ECh. 18 - Prob. 18.54ECh. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60ECh. 18 - Prob. 18.61ECh. 18 - Prob. 18.62ECh. 18 - Prob. 18.63ECh. 18 - Prob. 18.64ECh. 18 - Prob. 18.65ECh. 18 - Prob. 18.66ECh. 18 - Prob. 18.67ECh. 18 - Prob. 18.68ECh. 18 - Prob. 18.69ECh. 18 - Prob. 18.70ECh. 18 - Prob. 18.71ECh. 18 - When a doughnut is placed on a napkin, the napkin...Ch. 18 - Fats belong to the class of organic compounds...Ch. 18 - Identify each of the following characteristics as...Ch. 18 - Identify which sex hormones testosterone,...Ch. 18 - Prob. 18.76ECh. 18 - In diseases of the gallbladder, which of the...Ch. 18 - Steroids are classified as: a.carbohydrates....Ch. 18 - Accumulation of cholesterol leads to the hardening...Ch. 18 - Cholesterol, in spite of its bad reputation, is an...Ch. 18 - Bile is manufactured in the: a. duodenum. b....Ch. 18 - The basic structure of cell membrane is a: a....Ch. 18 - The mineralocorticoid _____ is a product of the...Ch. 18 - Prob. 18.84ECh. 18 - Prob. 18.85E
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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