a)
Interpretation: The balanced
Concept introduction: Bronsted-Lowry acid will donate a proton to the water. The oxygen in the water molecule will have lone pair of electrons which will accept the proton from the acid-forming hydronium ion
b)
Interpretation: The balanced chemical reaction and the expression for
Concept introduction: Bronsted-Lowry acid will donate a proton to the water. The oxygen in the water molecule will have lone pair of electrons which will accept the proton from the acid-forming hydronium ion
c)
Interpretation: The balanced chemical reaction and the expression for
Concept introduction: Bronsted-Lowry acid will donate a proton to the water. The oxygen in the water molecule will have lone pair of electrons which will accept the proton from the acid-forming hydronium ion
d)
Interpretation: The balanced chemical reaction and the expression for
Concept introduction: Bronsted-Lowry acid will donate a proton to the water. The oxygen in the water molecule will have lone pair of electrons which will accept the proton from the acid-forming hydronium ion
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CHEMISTRY MOLECULAR NATURE OF MATTER
- To measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent that is a weaker acid than water. One such solvent is liquid ammonia. (a) Write a chemical equation for the autoionization of ammonia. (b) What is the strongest acid and base that can exist in liquid ammonia? (c) Will a solution of HCI in liquid ammonia be a strong electrical conductor, a weak conductor, or a nonconductor? (d) Oxide ion (O2) is a stronger base than the amide ion (NH2). Write an equation for the reaction of O2 with NH3 in liquid ammonia. Will the equilibrium favor products or reactants?arrow_forwardWrite the reaction and the corresponding Kb equilibrium expression for each of the following substances acting as bases in water. a. NH3 b. C5H5Narrow_forwardWrite the reaction and the corresponding Kb equilibrium expression for each of the following substances acting as bases in water. a. aniline, C6H5NH2 b. dimethylamine, (CH3)2NHarrow_forward
- Ethanol (ethyl alcohol), CH3CH2OH, can act as a BrnstedLowry acid. Write the chemical equation for the reaction of ethanol as an acid with hydroxide ion, OH. Ethanol can also react as a BrnstedLowry base. Write the chemical equation for the reaction of ethanol as a base with hydronium ion, H3O+. Explain how you arrived at these chemical equations. Both of these reactions can also be considered Lewis acid base reactions. Explain this.arrow_forwardPure liquid ammonia ionizes in a manner similar to that of water. (a) Write the equilibrium for the autoionization of liquid ammonia. (b) Identify the conjugate acid form and the base form of the solvent. (c) Is NaNH2 an acid or a base in this solvent? (d) Is ammonium bromide an acid or a base in this solvent?arrow_forwardIn each of the following acid-base reactions, identify the Brnsted acid and base on the left and their conjugate partners on the right. (a) HCO2H(aq) + H2O() HCO2(aq) + H3O+(aq) (b) NH3(aq) + H2S(aq) NH4+(aq) + HS(aq) (c) HSO4(aq) + OH(aq) SO42(aq) + H2O+()arrow_forward
- A hydrogen atom in the organic base pyridine, C5H5N, can be substituted by various atoms or groups to give XC5H4N, where X is an atom such as Cl or a group such as CH3. The following table gives Ka values for the conjugate acids of a variety of substituted pyridines. (a) Suppose each conjugate acid is dissolved in sufficient water to give a 0.050 M solution. Which solution would have the highest pH? The lowest pH? (b) Which of the substituted pyridines is the strongest Brnsted base? Which is the weakest Brnsted base?arrow_forwardWhich of the terms weak, strong, monoprotic, diprotic, and triprotic characterize(s) each of the following acids? More than one term may apply in a given situation. a. HC3H3O3 b. HCN c. H2SO4 d. H2SO3arrow_forwardNicotinic acid, C6H5NO2, is found in minute amounts in all living cells, hut appreciable amounts occur in liver, yeast, milk, adrenal glands, white meat, and corn. Whole wheat (lour contains about 60. 0g per gram of flour. One gram (1.00 g) of the acid dissolves in water to give 60. mL of solution having a pH of 2.70. What is the approximate value of Ka for the acid? Nicotinic acidarrow_forward
- Which of each pair of acids is stronger? Why? (a) HClO3, HClO4 (b) H2S, H2Searrow_forwardState whether 1 M solutions of the following salts in water are acidic, basic, or neutral. (a) K2CO3 (b) NH4F (c) LiH2PO4 (d) NaNO2(e) Ba(ClO4)2arrow_forwardIn each of the following acid-base reactions, identify the Brnsted acid and base on the left and their conjugate partners on the right. (a) C2H5N(aq) + CH3CO2H(aq) C5H5NH+(aq) + CH3CO2(aq) (b) N2H4(aq) + HSO4(aq) N2H5+(aq) + SO42(aq) (c) [Al(H2O)6]3+ (aq) + OH(aq) [Al(H2O)5OH]2+ (aq) + H2O+()arrow_forward
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