Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Chapter 18, Problem 18.18E
Interpretation Introduction
Interpretation:
The process that is used to prepare margarines and cooking shortenings from vegetable oils is to be stated.
Concept introduction:
Fats and oils are triglycerides formed by the reaction of fatty acids with glycerol. They are hydrophobic in nature, so they are insoluble in water but soluble in organic solvents. Fats are solid triglycerides and oils are liquid triglycerides at room temperature.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 18 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 18 - What is the basis for deciding if a substance is a...Ch. 18 - List two major functions of lipids in the human...Ch. 18 - What functional group is common to all...Ch. 18 - Prob. 18.4ECh. 18 - Prob. 18.5ECh. 18 - Describe four structural characteristics exhibited...Ch. 18 - Describe the structure of a micelle formed by the...Ch. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Explain why the melting points of unsaturated...
Ch. 18 - What structural feature of a fatty acid is...Ch. 18 - How are fats and oils structurally similar? How...Ch. 18 - From Figure 18.7, arrange the following substances...Ch. 18 - Draw the structure of a triglyceride that contains...Ch. 18 - Prob. 18.15ECh. 18 - The percentage of fatty acid composition of two...Ch. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Why is the hydrogenation of vegetable oils of...Ch. 18 - Prob. 18.21ECh. 18 - Write reactions to show how each of the following...Ch. 18 - Draw the structure of a wax formed from oleic acid...Ch. 18 - Prob. 18.24ECh. 18 - Draw the structure of a wax formed from stearic...Ch. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Draw the general block diagram structure of a...Ch. 18 - Draw the structure of a phosphoglyceride...Ch. 18 - Describe two biological roles served by the...Ch. 18 - Prob. 18.31ECh. 18 - What is the structural difference between a...Ch. 18 - Prob. 18.33ECh. 18 - Prob. 18.34ECh. 18 - List two structural differences between...Ch. 18 - Prob. 18.36ECh. 18 - Describe the structural similarities and...Ch. 18 - Give another name for glycolipids. In what tissues...Ch. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - How does the polarity of the phosphoglycerides...Ch. 18 - Prob. 18.42ECh. 18 - Prob. 18.43ECh. 18 - Prob. 18.44ECh. 18 - Explain how bile salts aid in the digestion of...Ch. 18 - Prob. 18.46ECh. 18 - Prob. 18.47ECh. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Prob. 18.50ECh. 18 - How are testosterone and progesterone structurally...Ch. 18 - Prob. 18.52ECh. 18 - Prob. 18.53ECh. 18 - Prob. 18.54ECh. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60ECh. 18 - Prob. 18.61ECh. 18 - Prob. 18.62ECh. 18 - Prob. 18.63ECh. 18 - Prob. 18.64ECh. 18 - Prob. 18.65ECh. 18 - Prob. 18.66ECh. 18 - Prob. 18.67ECh. 18 - Prob. 18.68ECh. 18 - Prob. 18.69ECh. 18 - Prob. 18.70ECh. 18 - Prob. 18.71ECh. 18 - When a doughnut is placed on a napkin, the napkin...Ch. 18 - Fats belong to the class of organic compounds...Ch. 18 - Identify each of the following characteristics as...Ch. 18 - Identify which sex hormones testosterone,...Ch. 18 - Prob. 18.76ECh. 18 - In diseases of the gallbladder, which of the...Ch. 18 - Steroids are classified as: a.carbohydrates....Ch. 18 - Accumulation of cholesterol leads to the hardening...Ch. 18 - Cholesterol, in spite of its bad reputation, is an...Ch. 18 - Bile is manufactured in the: a. duodenum. b....Ch. 18 - The basic structure of cell membrane is a: a....Ch. 18 - The mineralocorticoid _____ is a product of the...Ch. 18 - Prob. 18.84ECh. 18 - Prob. 18.85E
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