EBK CHEMICAL PRINCIPLES
EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 8220101425812
Author: DECOSTE
Publisher: Cengage Learning US
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Chapter 18, Problem 106AE
Interpretation Introduction

Interpretation: The overlapping of d-orbital and p-orbital to form p-bond in H3PO3

molecule needs to be explained with the given structures:

  EBK CHEMICAL PRINCIPLES, Chapter 18, Problem 106AE

Concept Introduction:

Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.

The shape or geometry of molecule can be predicted with the help of hybridization and VSEPR theory. It can be checked with the below formula:

  Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

Chapter 18 Solutions

EBK CHEMICAL PRINCIPLES

Ch. 18 - Prob. 11ECh. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - Prob. 16ECh. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - Prob. 23ECh. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Prob. 43ECh. 18 - Prob. 44ECh. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - Prob. 47ECh. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - The synthesis of ammonia gas from nitrogen gas...Ch. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Prob. 63ECh. 18 - Prob. 64ECh. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Prob. 67ECh. 18 - Prob. 68ECh. 18 - Prob. 69ECh. 18 - Prob. 70ECh. 18 - Prob. 71ECh. 18 - Prob. 72ECh. 18 - Prob. 73ECh. 18 - Prob. 74ECh. 18 - Prob. 75ECh. 18 - Prob. 76ECh. 18 - Prob. 77ECh. 18 - Prob. 78ECh. 18 - Prob. 79ECh. 18 - Prob. 80ECh. 18 - Prob. 81ECh. 18 - Prob. 82ECh. 18 - Prob. 83ECh. 18 - Prob. 84ECh. 18 - Prob. 85ECh. 18 - Prob. 86ECh. 18 - Prob. 87ECh. 18 - Prob. 88ECh. 18 - Prob. 89ECh. 18 - Prob. 90AECh. 18 - Prob. 91AECh. 18 - Prob. 92AECh. 18 - Prob. 93AECh. 18 - Prob. 94AECh. 18 - Prob. 95AECh. 18 - Prob. 96AECh. 18 - Prob. 97AECh. 18 - Prob. 98AECh. 18 - Prob. 99AECh. 18 - Prob. 100AECh. 18 - Prob. 101AECh. 18 - Prob. 102AECh. 18 - Prob. 103AECh. 18 - Prob. 104AECh. 18 - Prob. 105AECh. 18 - Prob. 106AECh. 18 - Prob. 107AECh. 18 - Prob. 108AECh. 18 - Prob. 109AECh. 18 - Prob. 110AECh. 18 - Prob. 111AECh. 18 - Prob. 112AECh. 18 - Hydrogen gas is being considered as a fuel for...Ch. 18 - Prob. 114AECh. 18 - Prob. 115AECh. 18 - Prob. 116AECh. 18 - Prob. 117AECh. 18 - Prob. 118AECh. 18 - Prob. 119AECh. 18 - What is the molecular structure for each of the...Ch. 18 - Prob. 121AECh. 18 - Prob. 122AECh. 18 - Prob. 123CPCh. 18 - Prob. 124CPCh. 18 - Prob. 125CPCh. 18 - Prob. 126CPCh. 18 - Prob. 127CPCh. 18 - Prob. 128CPCh. 18 - Prob. 129CPCh. 18 - Prob. 130CPCh. 18 - Prob. 131CPCh. 18 - Prob. 132CPCh. 18 - Prob. 133CP
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