Interpretation:
The reason why the many reactions in which both reactants and products are in the solution phase has to be explained.
Concept Introduction:
Entropy is a
Where,
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CHEMISTRY (LOOSELEAF) >CUSTOM<
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- The vapor-liquid reactive equilibria for ethyl lactate synthesis follows the expressionlog K = 7.893 – (2.4312 x 103)K/Tbetween 83.12 °C and 101.54 °C. What are the ΔH°rxn, ΔG°rxn, and ΔS°rxn at 85 °C?Ind. Eng. Chem. Res. 2008, 47, 5, 1453–1463arrow_forwardFor a gascous reaction, standard conditions are 298 K and a partial pressure of 1 atm for all species. For the reaction CH, (g) + H,(g) = 2CH,(g) the standard change in Gibbs free energy is AG = -69.0 kJ/mol. What is AG for this reaction at 298 K when the partial pressures are PeH, = 0.150 atm, P, = 0.300 atm, and Pau, = 0.800 atm? kJ/mol AG =arrow_forwardFor the reaction 2 PbO (s) + 2 SO2 (g) 2 PbS (s) + 3 O2 (g), it can be calculated from AG°F values that AG°298 = %3D +780.8 kJ. What is AG (in kJ) at 298 K when the pressures of the gases are P(SO2) = 120 atm and P(O2) = 3.1 x 107 atm? O - 916 + 916 + 732 O + 722 O + 646arrow_forward
- Determine kc and kp at 298 Karrow_forwardDetermine kc and kp at 298 Karrow_forwardCaCO3 (s) dissociates in a closed system according to the reaction: CaCO, (s) = CaO(s) +CO, (g) 3 2 Assuming the reaction is in thermodynamic equilibrium, the degree(s) of freedom. F = when Ass CaCO,(s) dissociates in a closed system according to the reaction: CaCO(s) Cao(s) + CO2(g) pera A Assuming the reaction is in thermodynamic equilibrium, the degree(s) of freedom. F- eta 20arrow_forward
- Calculate AGxn for the given reaction at 700 K under the given conditions + 3 H₂(g) → 2 NH3(g) AGº = +46.4 kJ N₂(g) Substance N₂(g) H₂(g) NH,(g) P, atm 33 99 2.0arrow_forwardChemical Equilibrium. a) Briefly describe why (or how) it is possible to have an absolute value for the entropy of a system. b) Write appropriate inequalities for Gibbs free energy, Entropy and the Reaction Quotient that determine the direction of spontaneous change for forward, reverse or equilibrium processes. c) Briefly describe what you expect to occur as a function of time at a “single molecule" level for the chemical reaction AB=A +B9) at equilibrium. d) For the case of c how would you determine that the system is not at equilibrium?arrow_forwardWhen a neutralization reaction was carried out using 100.0 mL of 0.7890M NH3 water and 100.0 mL of 0.7940M acetic acid, ΔT was found to be 4.76 °C. The specific heat of the reaction mixture was 4.104 J g-l K-1 and its density was 1.03 g mL-1. The calorimeter constant was 3.36 JK-1 a) Calculate ΔH neutralization for the reaction of NH3 and acetic acid. b) At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.50 °C low. What effect would this thermometer reading have on the reported DH neutralization calculated above? c) When the temperature-time data graph was reviewed, it was found that an error had been made in determining ΔT. Instead of 4.76 °C, ΔT was actually 4.70 °C. Based on this change only, calculate the correct ΔH neutralization for the reaction of NH3, and acetic acid. d) Calculate the percent error for the correct ΔH neutralization if aΔ DT of 4.76 °C had been used.…arrow_forward
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