CHEMISTRY (LOOSELEAF) >CUSTOM<
CHEMISTRY (LOOSELEAF) >CUSTOM<
13th Edition
ISBN: 9781264348992
Author: Chang
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 17, Problem 17.28QP

The equilibrium constant (KP) for the reaction

H 2 ( g ) + CO 2 ( g ) H 2 O ( g ) + CO ( g )

is 4.40 at 2000 K. (a) Calculate ΔG° for the reaction. (b) Calculate ΔG for the reaction when the partial pressures are P H 2 = 0.25 atm, P CO 2 = 0.78 atm, P H 2 O = 0.66 atm, and PCO = 1.20 atm.

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2. Consider the following equilibrium: C (s) + H,O (g) = CÓ (g) + H, (g), AH® = +131.3 kJ-mol·' (1) Please write the expression of reaction quotient K. (2) Use Le Chatelier's Principle to state and explain the effect on the equilibrium when: (a) the pressure of H2O is increased; (b) the temperature is increased; (c) the concentration of the H, is increased; (d) The total pressure is increased by decreasing the volume. 作答
Calculate ΔG° for each of the following reactions from the equilibrium constant at the temperature given.(a) Cl2(g) + Br2(g) ⟶ 2BrCl(g)                  T = 25 °C          Kp = 4.7 × 10−2(b) 2SO2(g) + O2(g) ⇌ 2SO3(g)                 T = 500 °C       Kp = 48.2(c) H2 O(l) ⇌ H2 O(g)                                T = 60 °C          Kp = 0.196 atm(d) CoO(s) + CO(g) ⇌ Co(s) + CO2(g)       T = 550 °C        Kp = 4.90 × 102(e) CH3 NH2(aq) + H2 O(l) ⟶ CH3 NH3+(aq) + OH−(aq)                                                                                                 T = 25 °C          Kp = 4.4 × 10−4(f) PbI2(s) ⟶ Pb2+(aq) + 2I−(aq)             T = 25 °C          Kp = 8.7 × 10−9
(5b) Write the expression for the equilibrium constant Kp for the following reaction.Enclose pressures in parentheses and do NOT write the chemical formula as a subscript. For example, enter (PNH3 )2 as (P NH3)2. If either the numerator or denominator is 1, please enter 1   2 CuCl2(s)   ↔   2 CuCl(s) + Cl2(g)           K   =     (8c) Consider the following reaction where Kc = 6.50×10-3 at 298 K: 2 NOBr (g) 2 NO (g) + Br2 (g) A reaction mixture was found to contain 9.96×10-2 moles of NOBr (g), 4.61×10-2 moles of NO (g), and 4.42×10-2 moles of Br2 (g), in a 1.00 liter container.Indicate True (T) or False (F) for each of the following: 1. In order to reach equilibrium NOBr(g) must be consumed .2. In order to reach equilibrium Kc must decrease .3. In order to reach equilibrium NO must be produced .4. Qc is less than Kc.5. The reaction is at equilibrium. No further reaction will occur.

Chapter 17 Solutions

CHEMISTRY (LOOSELEAF) >CUSTOM<

Ch. 17.5 - Prob. 2RCFCh. 17.5 - Prob. 3RCFCh. 17.5 - Prob. 4RCFCh. 17.6 - Calculate the equilibrium constant (KP) for the...Ch. 17.6 - Prob. 7PECh. 17.6 - Prob. 8PECh. 17.6 - A reaction has a positive H and a negative S.Is...Ch. 17.6 - For the reaction A(g)+B(g)C(g) G = 33.3 kJ/mol at...Ch. 17.6 - For the reaction C(aq)A(aq)+B(aq) G = 1.95 kJ/mol...Ch. 17 - Explain what is meant by a spontaneous process....Ch. 17 - State which of the following processes are...Ch. 17 - Prob. 17.3QPCh. 17 - Define entropy. What are the units of entropy?Ch. 17 - How does the entropy of a system change for each...Ch. 17 - State the second law of thermodynamics in words...Ch. 17 - State the third law of thermodynamics and explain...Ch. 17 - For each pair of substances listed here, choose...Ch. 17 - Arrange the following substances (1 mole each) in...Ch. 17 - Using the data in Appendix 2, calculate the...Ch. 17 - Using the data in Appendix 2, calculate the...Ch. 17 - Without consulting Appendix 2, predict whether the...Ch. 17 - Prob. 17.14QPCh. 17 - Define free energy. What are its units?Ch. 17 - Why is it more convenient to predict the direction...Ch. 17 - Calculate G for the following reactions at 25C:...Ch. 17 - Calculate G for the following reactions at 25C:...Ch. 17 - From the values of H and S, predict which of the...Ch. 17 - Find the temperatures at which reactions with the...Ch. 17 - Explain the difference between G and G.Ch. 17 - Explain why Equation (17.14). is of great...Ch. 17 - Calculate KP for the following reaction at 25C:...Ch. 17 - For the autoionization of water at 25C,...Ch. 17 - Consider the following reaction at 25C:...Ch. 17 - Calculate G and KP for the following equilibrium...Ch. 17 - (a) Calculate G and KP for the following...Ch. 17 - The equilibrium constant (KP) for the reaction...Ch. 17 - Consider the decomposition of calcium carbonate:...Ch. 17 - The equilibrium constant KP for the reaction...Ch. 17 - At 25C, G for the process H2O(l)H2O(g) is 8.6...Ch. 17 - Calculate G for the process C(diamond)C(graphite)...Ch. 17 - What is a coupled reaction? What is its importance...Ch. 17 - What is the role of ATP in biological reactions?Ch. 17 - Referring to the metabolic process involving...Ch. 17 - In the metabolism of glucose, the first step is...Ch. 17 - Explain the following nursery rhyme in terms of...Ch. 17 - Calculate G for the reaction H2O(l)H+(aq)+OH(aq)...Ch. 17 - Calculate the Ssoln for the following processes:...Ch. 17 - The following reaction is spontaneous at a certain...Ch. 17 - Which of the following thermodynamic functions are...Ch. 17 - A student placed 1 g of each of three compounds A,...Ch. 17 - Use the data in Appendix 2 to calculate the...Ch. 17 - Predict the signs of H, S, and G of the system for...Ch. 17 - Prob. 17.45QPCh. 17 - Ammonium nitrate (NH4NO3) dissolves spontaneously...Ch. 17 - Calculate the equilibrium pressure of CO2 due to...Ch. 17 - Prob. 17.48QPCh. 17 - Prob. 17.49QPCh. 17 - Carbon monoxide (CO) and nitric oxide (NO) are...Ch. 17 - Prob. 17.51QPCh. 17 - Use the thermodynamic data in Appendix 2 to...Ch. 17 - Consider the reaction A B + C at 298 K. Given...Ch. 17 - The Ksp of AgCl is given in Table 16.2. What is...Ch. 17 - Prob. 17.55QPCh. 17 - Water gas, a mixture of H2 and CO, is a fuel made...Ch. 17 - Consider the following Brnstead acid-base reaction...Ch. 17 - Crystallization of sodium acetate from a...Ch. 17 - Prob. 17.59QPCh. 17 - A certain reaction is spontaneous at 72C. If the...Ch. 17 - Predict whether the entropy change is positive or...Ch. 17 - 17.62The reaction NH3(g)+HCl(g)NH4Cl(s) proceeds...Ch. 17 - Prob. 17.63QPCh. 17 - The molar heat of vaporization of ethanol is 39.3...Ch. 17 - Prob. 17.65QPCh. 17 - In the Mond process for the purification of...Ch. 17 - Calculate G and KP for the following processes at...Ch. 17 - Calculate the pressure of O2 (in atm) over a...Ch. 17 - Prob. 17.69QPCh. 17 - Prob. 17.70QPCh. 17 - Consider the reaction N2(g)+O2(g)2NO(g) Given that...Ch. 17 - Prob. 17.72QPCh. 17 - Prob. 17.73QPCh. 17 - Prob. 17.74QPCh. 17 - Prob. 17.75QPCh. 17 - Prob. 17.76QPCh. 17 - Prob. 17.77QPCh. 17 - Prob. 17.78QPCh. 17 - Prob. 17.79QPCh. 17 - Prob. 17.80QPCh. 17 - Prob. 17.81QPCh. 17 - Prob. 17.82QPCh. 17 - Prob. 17.83QPCh. 17 - Prob. 17.84QPCh. 17 - Shown here are the thermodynamic data for ethanol:...Ch. 17 - The reaction shown here is spontaneous at a...Ch. 17 - Consider two carboxylic acids (acids that contain...Ch. 17 - Many hydrocarbons exist as structural isomers,...Ch. 17 - Use the thermodynamic data in Appendix 2 to...Ch. 17 - A rubber band is stretched vertically by attaching...Ch. 17 - One of the steps in the extraction of iron from...Ch. 17 - Derive the equation G=RTln(Q/K) where Q is the...Ch. 17 - The sublimation of carbon dioxide at 78C is...Ch. 17 - Entropy has sometimes been described as times...Ch. 17 - Referring to Figure 17.1, we see that the...Ch. 17 - A student looked up the Gf, Hf, and S values for...Ch. 17 - Consider the following reaction at 298 K:...Ch. 17 - As an approximation, we can assume that proteins...Ch. 17 - Which of the following are not state functions: S,...Ch. 17 - Which of the following is not accompanied by an...Ch. 17 - Hydrogenation reactions (for example, the process...Ch. 17 - Give a detailed example of each of the following,...Ch. 17 - At 0 K, the entropy of carbon monoxide crystal is...Ch. 17 - Comment on the correctness of the analogy...Ch. 17 - The standard enthalpy of formation and the...Ch. 17 - In chemistry, the standard state for as solution...Ch. 17 - The following diagram shows the variation of the...Ch. 17 - Consider the gas-phase reaction between A2 (green)...Ch. 17 - The KP for the reaction N2+3H22NH3 is 2.4 103 at...Ch. 17 - The table shown here lists the ion-product...Ch. 17 - Draw the missing distributions in Figure 17.2....Ch. 17 - The reaction NH3(g)+HCl(g)NH4Cl(s) is spontaneous...Ch. 17 - The boiling point of diethyl ether is 34.6C....Ch. 17 - Nicotine is the compound in tobacco responsible...Ch. 17 - Estimate S for the process depicted in Figure...Ch. 17 - At what point in the series HOnH(g) (n = 1, 2, 3,...
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