A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed. Concept introduction: One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp 3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

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Answer 1

Question

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

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Answer 2

Question

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

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Answer 3

Question

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

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Answer 4

Question

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

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Answer 5

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

Answer 6

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

Answer 7

Chapter 17.2, Problem 17.2P

Interpretation Introduction

Interpretation:

A mechanism for the aluminum chloride-catalysed reaction of benzene with chlorine has to be proposed.

Concept introduction:

One of the most important reactions of aromatic compound is electrophilic aromatic substitution. The pi electron cloud of benzene readily attacks a strong electrophile which results in the formation of a carbocation. This carbocation is resonance stablised. It is known as a sigma complex. This complex is not aromatic due to sp3 hybrid carbon atom. The aromaticity is regained by the loss of proton on the tetrahedral carbon atom.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 17.1 - Prob. 17.1P Ch. 17.2 - Prob. 17.2P Ch. 17.3 - Prob. 17.3P Ch. 17.4 - Use resonance forms to show that the dipolar sigma...Ch. 17.6A - Prob. 17.5P Ch. 17.6A - Prob. 17.6P Ch. 17.6B - Propose a mechanism for the brommation of...Ch. 17.6B - Prob. 17.8P Ch. 17.6B - Prob. 17.9P Ch. 17.7 - Prob. 17.10P

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Chapter 17 Solutions