![Organic Chemistry (9th Edition)](https://www.bartleby.com/isbn_cover_images/9780321971371/9780321971371_largeCoverImage.gif)
(a)
To determine: The major product that is formed by reaction of benzene with
Interpretation: The major product that is formed by reaction of benzene with
Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.
(a)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with
Explanation of Solution
The major product that is formed by reaction of benzene with
Figure
In the above reaction, benzene reacts with
(b)
To determine: The major product that is formed by reaction of benzene with
Interpretation: The major product that is formed by reaction of benzene with
Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.
(b)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with
Explanation of Solution
The major product that is formed by reaction of benzene with
Figure
In the above reaction, benzene reacts with
(c)
To determine: The major product that is formed by reaction of benzene with isobutyl alcohol in the presence of
Interpretation: The major product that is formed by reaction of benzene with isobutyl alcohol in the presence of
Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alcohol in the presence of
(c)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with isobutyl alcohol in the presence of
Explanation of Solution
The major product that is formed by reaction of benzene with isobutyl alcohol in the presence of
Figure
In the above reaction, the primary carbocation that is generated by the protonation of isobutyl alcohol by
In the second step, this electrophilic carbocation reacts with benzene in the presence of
(d)
To determine: The major product that is formed by reaction of benzene with bromine in the presence of a nail.
Interpretation: The major product that is formed by reaction of benzene with bromine in the presence of a nail is to be predicted.
Concept introduction: The reaction that includes the addition of one or more bromine atoms in a compound is known as bromination reaction. Bromination reaction is a type of halogenation reaction.
(d)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with bromine in the presence of a nail is shown as follows.
Explanation of Solution
The major product that is formed by reaction of benzene with bromine in the presence of a nail is shown in Figure
Figure
In the above reaction, bromination of benzene ring occurs to form bromobenzene as the desired product.
(e)
To determine: The major product that is formed by reaction of benzene with isobutylene in the presence of
Interpretation: The major product that is formed by reaction of benzene with isobutylene in the presence of
Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with
(e)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with isobutylene in the presence of
Explanation of Solution
The major product that is formed by reaction of benzene with isobutylene in the presence of
Figure
In the above reaction, benzene reacts with isobutylene in the presence of
(f)
To determine: The major product that is formed by reaction of benzene with fuming sulphuric acid.
Interpretation: The major product that is formed by reaction of benzene with fuming sulphuric acid is to be predicted.
Concept introduction: The process of attaching
(f)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with fuming sulphuric acid is shown as follows.
Explanation of Solution
The major product that is formed by reaction of benzene with fuming sulphuric acid is shown in Figure
Figure
In the above reaction, benzene reacts with fuming sulphuric acid to form as the desired sulfonated product.
(g)
To determine: The major product that is formed by reaction of benzene with
Interpretation: The major product that is formed by reaction of benzene with
Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.
(g)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with
Explanation of Solution
The major product that is formed by reaction of benzene with
Figure
In the above reaction, benzene reacts with
(h)
To determine: The major product that is formed by reaction of benzene with benzoyl chloride in the presence of
Interpretation: The major product that is formed by reaction of benzene with benzoyl chloride in the presence of
Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.
(h)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with benzoyl chloride in the presence of
Explanation of Solution
The major product that is formed by reaction of benzene with benzoyl chloride in the presence of
Figure
In the above reaction, benzene reacts with benzoyl chloride in the presence of
(i)
To determine: The major product that is formed by reaction of benzene with iodine molecule in the presence of
Interpretation: The major product that is formed by reaction of benzene with iodine molecule in the presence of
Concept introduction: The reaction that includes the addition of one or more than one halogen atoms in a compound is known as halogenation reaction.
(i)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with iodine molecule in the presence of
Explanation of Solution
The major product that is formed by reaction of benzene with iodine molecule in the presence of
Figure
In the above halogenations reaction, benzene reacts with iodine molecule in the presence of
(j)
To determine: The major product that is formed by reaction of benzene with nitric acid and sulphuric acid.
Interpretation: The major product that is formed by reaction of benzene with nitric acid and sulphuric acid is to be predicted.
Concept introduction: The reaction that involves the addition of a nitro group on an alkyl or an aromatic compound in the presence of concentrated nitric acid and sulphuric acid is known as nitration reaction.
(j)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with nitric acid and sulphuric acid is shown as follows.
Explanation of Solution
The major product that is formed by reaction of benzene benzene with nitric acid and sulphuric acid is shown in Figure
Figure
In the above nitration reaction, benzene reacts with concentrated nitric acid and sulphuric acid that forms nitrobenzene as the desired product.
(k)
To determine: The major product that is formed by reaction of benzene with carbon monoxide in the presence of
Interpretation: The major product that is formed by reaction of benzene with carbon monoxide in the presence of
Concept introduction: The synthesis in which
(k)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with carbon monoxide in the presence of
Explanation of Solution
The major product that is formed by reaction of benzene with carbon monoxide in the presence of
Figure
In the above reaction, benzene reacts with benzoyl carbon monoxide in the presence of
(l)
To determine: The major product that is formed by reaction of benzene with
Interpretation: The major product that is formed by reaction of benzene with
Concept introduction: Friedel-Crafts acylation permits the synthesis of acylated products by the reaction of arenes with acyl chlorides in the presence of
(l)
![Check Mark](/static/check-mark.png)
Answer to Problem 17.50SP
The major product that is formed by reaction of benzene with
Explanation of Solution
The major product that is formed by reaction benzene with
Figure
In the above reaction, benzene reacts with
Want to see more full solutions like this?
Chapter 17 Solutions
Organic Chemistry (9th Edition)
- 10- 4000 20 20 30- %Reflectance 60 50- 09 60- 40- Date: Thu Feb 06 17:30:02 2025 (GMT-05:0(UnknownP Scans: 8 Resolution: 2.000 70 70 88 80 3500 3000 2500 90 100 00 Wavenumbers (cm-1) 2000 1500 2983.10 2359.13 1602.52 1584.22 1451.19 1391.87 1367.07 1314.37 1174.34 1070.13 1027.33 1714.16 1269.47 1000 1106.08 1001.14 937.02 873.60 850.20 780.22 686.91 674.38 643.09 617.98 02/06/25 16:38:20arrow_forwardd. Draw arrow-pushing mechanism for an enzymatic retro-aldol reaction of the following hexose. Use B: and/or HA as needed. OH OH سية HO OH OHarrow_forward4. Calculate the wavelength of a photon needed to excite a transition between neighbouring energy levels of a harmonic oscillator of effective mass equal to that of an oxygen atom and with a force constant of 544 N m¹.arrow_forward
- 2. Identify the strongest type of intermolecular force that exists between each pair of compounds: a. Ammonium chloride / H₂O b. OH C. d.arrow_forwardREPORT FOR EXPERIMENT 9 (continued) NAME F. Solubility vs. Temperature; Saturated and Unsaturated Solutions Data Table: Circle the choices which best describe your observations. NaCl 1.0 g +5 mL water 1.0 g +5 mL water +1.4 g dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? 2.4 g +5 mL water +heat dissolved completely? yes/no saturated or unsaturated? 2.4 g +5 mL water after cooling dissolved completely? yes/no saturated or unsaturated? NHC dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? dissolved completely? yes/no saturated or unsaturated? G. Ionic Reactions in Solution 1. Write the word and formula equations representing the chemical reaction that occurred between the barium chloride solution, BaCl,(aq), and the sodium sulfate solution, Na SO (aq). Word Equation: Formula Equation: 2. (a) Which of the…arrow_forwardIn the drawing areas below, draw the two most expected stable conformations of the following molecule: ייון Be sure your drawings make it possible to distinguish between the conformations. After you've drawn the conformations, answer the question below the drawing areas. Х S : ☐ ☑ 5arrow_forward
- Add curved arrows to show the forming and breaking of bonds in the reaction below. :Br: H 2 Add/Remove step ☑ H-Br: G હે Parrow_forwardPlease correct answer and don't use hand ratingarrow_forwardSafari File Edit View History Bookmarks Window Help く < mylabmastering.pearson.com Wed Feb 12 8:44 PM ✩ + Apple Q Bing Google SignOutOptions M Question 36 - Lab HW BI... P Pearson MyLab and Mast... P Course Home Error | bartleby b Answered: If the biosynth... Draw a free-radical mechanism for the following reaction, forming the major monobromination product: ScreenPal - 2022 CHEM2... Access Pearson 2 CH3 Br-Br CH H3 Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. Add charges where needed. Electron- flow arrows should start on the electron(s) of an atom or a bond and should end on an atom, bond, or location where a new bond should be created. Include all free radicals by right-clicking on an atom on the canvas and then using the Atom properties to select the monovalent radical. ▸ View Available Hint(s) 0 2 DE [1] H EXP. CONT. H. Br-Br H FEB 12arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305580350/9781305580350_smallCoverImage.gif)