
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 17.12, Problem 17.20CE
Interpretation Introduction
Interpretation:
Whether all metals corrode as readily as iron has to be predicted. The three metals that are expected to corrode as readily as iron have to be stated. The three metals that donot corrode easily have to be stated. The use of each three noncorroding metals has to be stated. An explanation as to why these metals fall into these two groups has to be stated.
Concept Introduction:
The corrosion is the conversion of metal to its metal oxides or hydroxides. Metals generally get corrode due to the
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On the next page is an LC separation of the parabens found in baby wash. Parabens are
suspected in a link to breast cancer therefore an accurate way to quantitate them is desired.
a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for
all the terms in your calculation.
b. Is this a "good" value for a capacity factor? Explain.
c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly
what values you used in your calculation.
MAU
| Methyl paraben
40
20
0
-2
Ethyl paraben n-Propyl paraben
n-Butyl paraben
App ID 22925
6
8
min
d. In Figure 4, each stationary phase shows some negative correlation between plate count
and retention factor. In other words, as k' increases, N decreases. Explain this relationship
between k' and N.
Plate Count (N)
4000
3500
2500
2000
1500
1000
Figure 4. Column efficiency (N) vs retention factor (k') for 22
nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000
Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain
k' less than 15, which was achieved for most solutes as follows: FMS
(30/70 A/W), PGC (60/40), COZ (80/20). Slightly different
compositions were used for the most highly retained solutes. All
columns were 50 mm × 4.6 mm id and packed with 5 um particles,
except for COZ, which was packed with 3 um particles. All other
chromatographic conditions were constant: column length 5 cm,
column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C,
and injection volume 0.5 μL
Log(k'x/K'ethylbenzene)
FMS
1.5
1.0
0.5
0.0
ཐྭ ཋ ཤྩ བྷྲ ;
500
0
5
10…
f. Predict how the van Deemter curve in Figure 7
would change if the temperature were raised
from 40 °C to 55 °C.
Figure 7. van Desmter curves in reduced coordinates for four
nitroalkane homologues (nitropropane, black; nitrobutane, red;
nitropentane, blue; and nitrohexane, green) separated on the FMS
phase. Chromatographic conditions: column dimensions 50 mm × 4.6
mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection
volume 0.5 and column temperature 40 °C. No corrections to the
plate heights have been made to account for extracolumn dispersion.
Reduced Plate Height (h)
°
20
40
60
Reduced Velocity (v)
8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and
standard are spiked with a fixed amount of toluene as an internal standard. The following data are
obtained:
Ppb benzene
Peak area benzene
Peak area toluene
10.0
252
376
Sample
533
368
What is the concentration of benzene in the sample?
Chapter 17 Solutions
Chemistry: The Molecular Science
Ch. 17.1 - Prob. 17.1ECh. 17.1 - Prob. 17.1PSPCh. 17.2 - Write oxidation and reduction half-reactions for...Ch. 17.2 - Prob. 17.2CECh. 17.3 - Prob. 17.3PSPCh. 17.3 - Prob. 17.3CECh. 17.3 - Prob. 17.4CECh. 17.4 - Which has the larger charge, 1.0 C or Avogadro's...Ch. 17.4 - Is it reasonable to conclude that a potential...Ch. 17.4 - Devise an experiment that would show that Zn is...
Ch. 17.4 - Given this reaction, its standard potential, and...Ch. 17.5 - Prob. 17.5PSPCh. 17.5 - Prob. 17.8CECh. 17.5 - Prob. 17.9CECh. 17.5 - Prob. 17.10CECh. 17.6 - Prob. 17.6PSPCh. 17.6 - Prob. 17.11ECh. 17.6 - Prob. 17.7PSPCh. 17.7 - Calculate the cell potential for the Zn(s) +...Ch. 17.7 - Prob. 17.9PSPCh. 17.8 - Prob. 17.12ECh. 17.8 - Prob. 17.13ECh. 17.8 - Prob. 17.14ECh. 17.10 - Predict the results of passing a direct electrical...Ch. 17.10 - In 1886. Henri Moissan was the first to prepare...Ch. 17.11 - In the commercial production of sodium metal by...Ch. 17.11 - Prob. 17.16CECh. 17.11 - Prob. 17.17ECh. 17.11 - Prob. 17.18CECh. 17.11 - Prob. 17.19ECh. 17.12 - Prob. 17.20CECh. 17.12 - Prob. 17.21CECh. 17 - Prob. 2SPCh. 17 - Prob. 1QRTCh. 17 - Prob. 2QRTCh. 17 - Prob. 3QRTCh. 17 - Prob. 4QRTCh. 17 - Identify each statement as true or false. Rewrite...Ch. 17 - Prob. 6QRTCh. 17 - Prob. 7QRTCh. 17 - Prob. 8QRTCh. 17 - Answer Question 8 again, but this time find a...Ch. 17 - Prob. 10QRTCh. 17 - Prob. 11QRTCh. 17 - For the reaction in Question 6, write balanced...Ch. 17 - Prob. 13QRTCh. 17 - Prob. 14QRTCh. 17 - Prob. 15QRTCh. 17 - Prob. 16QRTCh. 17 - Prob. 17QRTCh. 17 - For the reaction Cu2+(aq) + Zn(s) → Cu(s) + Zn2+...Ch. 17 - Prob. 19QRTCh. 17 - Prob. 20QRTCh. 17 - Prob. 21QRTCh. 17 - Prob. 22QRTCh. 17 - Draw a diagram of each cell. Label the anode, the...Ch. 17 - Prob. 24QRTCh. 17 - Prob. 25QRTCh. 17 - Prob. 26QRTCh. 17 - Prob. 27QRTCh. 17 - Prob. 28QRTCh. 17 - Prob. 29QRTCh. 17 - Prob. 30QRTCh. 17 - Prob. 31QRTCh. 17 - Consider these half-reactions: (a) Which is the...Ch. 17 - Consider these half-reactions: (a) Which is the...Ch. 17 - In principle, a battery could be made from...Ch. 17 - Prob. 35QRTCh. 17 - Hydrazine, N2H4, can be used as the reducing agent...Ch. 17 - Prob. 37QRTCh. 17 - Prob. 38QRTCh. 17 - Prob. 39QRTCh. 17 - Prob. 40QRTCh. 17 - Prob. 41QRTCh. 17 - Prob. 42QRTCh. 17 - Prob. 43QRTCh. 17 - Prob. 44QRTCh. 17 - Prob. 45QRTCh. 17 - Prob. 46QRTCh. 17 - Consider the voltaic cell 2 Ag+(aq) + Cd(s) 2...Ch. 17 - Consider a voltaic cell with the reaction H2(g) +...Ch. 17 - Calculate the cell potential of a concentration...Ch. 17 - Prob. 50QRTCh. 17 - Prob. 51QRTCh. 17 - Prob. 52QRTCh. 17 - Prob. 53QRTCh. 17 - NiCad batteries are rechargeable and are commonly...Ch. 17 - Prob. 55QRTCh. 17 - Prob. 56QRTCh. 17 - Prob. 57QRTCh. 17 - Hydrazine, N2H4, has been proposed as the fuel in...Ch. 17 - Consider the electrolysis of water in the presence...Ch. 17 - Prob. 60QRTCh. 17 - Prob. 61QRTCh. 17 - Prob. 62QRTCh. 17 - Identify the products of the electrolysis of a 1-M...Ch. 17 - Prob. 64QRTCh. 17 - Prob. 65QRTCh. 17 - Prob. 66QRTCh. 17 - Prob. 67QRTCh. 17 - Prob. 68QRTCh. 17 - Prob. 69QRTCh. 17 - Prob. 70QRTCh. 17 - Prob. 71QRTCh. 17 - Prob. 72QRTCh. 17 - Prob. 73QRTCh. 17 - Prob. 74QRTCh. 17 - Calculate how long it would take to electroplate a...Ch. 17 - Prob. 76QRTCh. 17 - Prob. 77QRTCh. 17 - Prob. 78QRTCh. 17 - Prob. 79QRTCh. 17 - Prob. 80QRTCh. 17 - Prob. 81QRTCh. 17 - Prob. 82QRTCh. 17 - Prob. 83QRTCh. 17 - Prob. 84QRTCh. 17 - Prob. 85QRTCh. 17 - Prob. 86QRTCh. 17 - Prob. 87QRTCh. 17 - Prob. 88QRTCh. 17 - You wish to electroplate a copper surface having...Ch. 17 - Prob. 90QRTCh. 17 - Prob. 91QRTCh. 17 - Prob. 92QRTCh. 17 - Prob. 93QRTCh. 17 - An electrolytic cell is set up with Cd(s) in...Ch. 17 - Prob. 95QRTCh. 17 - Prob. 96QRTCh. 17 - Prob. 97QRTCh. 17 - Prob. 98QRTCh. 17 - Prob. 99QRTCh. 17 - Prob. 100QRTCh. 17 - Prob. 101QRTCh. 17 - Prob. 102QRTCh. 17 - Prob. 103QRTCh. 17 - Prob. 104QRTCh. 17 - Prob. 105QRTCh. 17 - Prob. 106QRTCh. 17 - Prob. 107QRTCh. 17 - Prob. 108QRTCh. 17 - Prob. 109QRTCh. 17 - Prob. 110QRTCh. 17 - Prob. 111QRTCh. 17 - Prob. 17.ACPCh. 17 - Prob. 17.BCP
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