The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted. Concept introduction: Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl 3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 1

Question

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

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2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Answer 2

Question

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

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Answer 3

Question

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

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Answer 4

Question

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

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Answer 5

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 6

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

Answer 7

Chapter 17.11C, Problem 17.20P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

The synthesis in which aromatic compounds reacts with carbon monoxide, and HCl in the presence of AlCl3 (Lewis acid) to form an aromatic aldehyde compound.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used for the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 20

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 21

(h)

Interpretation Introduction

Interpretation:

The synthesis of given compound using Friedel-Crafts acylation, Clemmensen reduction or Gatterman-Koch synthesis is to be predicted.

Concept introduction:

Friedel-Crafts acylation permits the synthesis of monoacylated products by the reaction of arenes with acyl chlorides in the presence of AlCl3 (Lewis acid). This acylation reaction comes under the category of electrophilic aromatic substitution.

The reaction that is used in the reduction of a ketonic or an aldehydic compound into an alkane compound, using zinc amalgam and HCl, is known as Clemmensen reduction.

Answer 22

Expert Solution & Answer

Answer 23

Expert Solution & Answer

Answer 24

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Answer 25

Ch. 17.1 - Prob. 17.1P Ch. 17.2 - Prob. 17.2P Ch. 17.3 - Prob. 17.3P Ch. 17.4 - Use resonance forms to show that the dipolar sigma...Ch. 17.6A - Prob. 17.5P Ch. 17.6A - Prob. 17.6P Ch. 17.6B - Propose a mechanism for the brommation of...Ch. 17.6B - Prob. 17.8P Ch. 17.6B - Prob. 17.9P Ch. 17.7 - Prob. 17.10P

Solution Summary: The author explains Friedel-Crafts acylation, Clemmensen reduction, or Gatterman-Koch synthesis.

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Chapter 17 Solutions