An example for each of the given compounds has to be stated: A β -keto nitrile Concept introduction: In a β -keto nitrile , the keto group is placed at the β position of the cyanide group. In a β -diester , one ester group is at a β position to the second ester group. In a β -keto aldehyde , the keto group is placed at the β position to the aldehyde group.

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Answer 1

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Can the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left? ? starting material target If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area. Be sure you follow the standard ALEKS rules for submitting syntheses. + More... Note for advanced students: you may assume that you are using a large excess of benzene as your starting material. C :0 T Add/Remove step G

The following equations represent the formation of compound MX. What is the AH for the electron affinity of X (g)? X₂ (g) → 2X (g) M (s) → M (g) M (g) M (g) + e- AH = 60 kJ/mol AH = 22 kJ/mol X (g) + e-X (g) M* (g) +X (g) → MX (s) AH = 118 kJ/mol AH = ? AH = -190 kJ/mol AH = -100 kJ/mol a) -80 kJ b) -30 kJ c) -20 kJ d) 20 kJ e) 156 kJ

A covalent bond is the result of the a) b) c) d) e) overlap of two half-filled s orbitals overlap of a half-filled s orbital and a half-filled p orbital overlap of two half-filled p orbitals along their axes parallel overlap of two half-filled parallel p orbitals all of the above

Answer 2

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Answer 3

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Answer 4

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Answer 5

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 6

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 7

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 8

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 9

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 10

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 11

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17.1 - Prob. 1P Ch. 17.1 - Prob. 2P Ch. 17.1 - Prob. 3P Ch. 17.1 - Prob. 4P Ch. 17.1 - Rank the compounds in each of the following groups...Ch. 17.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 17.3 - Draw the enol tautomers for each of the following...Ch. 17.3 - Prob. 8P Ch. 17.4 - Prob. 9P Ch. 17.4 - Prob. 10P

Solution Summary: The author illustrates how the positions of carbon atoms in the compound can be visualized as given below.

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Chapter 17 Solutions