Three resonance structures of naphthalene have to be drawn and the reason for why C 1 − C 2 bond has a shorter bond length than C 2 − C 3 bond has to be given. Concept Introduction: Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital. Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy. Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types Double bonds: One sigma bond and one pi bond are together known as a double bond. Bond length is inversely proportional to the bond order. A higher bond order results in a shorter bond for a given pair of atoms.

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Answer 1

Question

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

C. NaOMe, Br Br

Answer 2

Question

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

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Answer 3

Question

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

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Answer 4

Question

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

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Answer 5

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

Answer 6

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

Answer 7

Chapter 17, Problem 65IP

(a)

Interpretation Introduction

Interpretation: Three resonance structures of naphthalene have to be drawn and the reason for why C1−C2 bond has a shorter bond length than C2−C3 bond has to be given.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

Answer 8

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

Answer 9

(b)

Interpretation Introduction

Interpretation: Five resonance structures of phenanthrene have to be drawn and the bond that has a shorter bond length has to be predicted using resonance structures of phenanthrene.

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Double bonds: One sigma bond and one pi bond are together known as a double bond.

Bond length is inversely proportional to the bond order.

A higher bond order results in a shorter bond for a given pair of atoms.

Answer 10

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

Answer 11

(c)

Interpretation Introduction

Interpretation: Product having molecular formula C14H10Br2 obtained when Br2 is treated with phenanthrene has to be drawn

Concept Introduction:

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule.

Bromination: In bromination reaction, bromine atom is introduced to a compound.

Answer 12

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Answer 15

Ch. 17.2 - Prob. 1LTS Ch. 17.2 - Prob. 1PTS Ch. 17.2 - Prob. 2PTS Ch. 17.2 - Prob. 3PTS Ch. 17.2 - Prob. 4PTS Ch. 17.2 - Prob. 5ATS Ch. 17.4 - Prob. 6CC Ch. 17.4 - Prob. 7CC Ch. 17.4 - Prob. 8CC Ch. 17.4 - Prob. 9CC

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