EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 17, Problem 17.56AP
Interpretation Introduction

Interpretation:

The reason for the variation in the stereochemistry of addition as the alkene structure varied is to be stated.

Concept introduction:

Addition of halogens into alkenes is stereoselective, that is, it depends upon the type of the alkene present. If the alkene is a cis-alkene, anti-addition of halide ions take place and a racemic mixture is formed. If the alkene is a trans-alkene, syn-addition of halide ions occur and a meso compound is formed.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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