(a) Interpretation: The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide , with D 2 O is to be stated. Concept introduction: Grignard reagent is an organometallic compound . In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

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Answer 1

Question

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Answer 2

Question

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

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Answer 3

Question

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

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Answer 4

Question

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

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Answer 5

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Answer 6

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Answer 7

Chapter 17, Problem 17.7P

Interpretation Introduction

(a)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product obtained from the reaction of Grignard reagent, prepared from the given alkyl halide, with D2O is to be stated.

Concept introduction:

Grignard reagent is an organometallic compound. In Grignard reagent, the magnesium metal is directly attached to the carbon atom. Therefore, the carbon atom behaves as anion. Therefore, the properties of the Grignard reagent are almost same as the carbanions.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains that Grignard reagent is an organometallic compound. The magnesium metal is directly attached to the carbon atom.

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Chapter 17 Solutions