(a) Interpretation: The reason as to why the trityl radical is an unusually stable radical is to be stated. Concept introduction: Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π - bonds or by interaction of the lone pair of electrons and π - bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Question

Want to see the full answer?

Answer 1

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

1. Refer to the compounds below to answer the following questions: CO₂Et 0 C. H O O₂N-CH2-C-CH3 0 OEt || 111 A. Indicate all the acidic hydrogens in Compounds I through IV. IV B. Indicate which hydrogens in Compound II are the most acidic. Explain your answer C. Choose the most acidic compound from Compounds I - IV. Explain your choice.

Show how you would accomplish the following transformations. More than one step may be required. ow all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3CH2C-CN CH3 CH3.

Show how you would accomplish the following transformations. More than one step may be required. now all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3 CH3CH2C-CN CH3

Answer 2

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 6

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 7

Chapter 17, Problem 17.54AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why the trityl radical is an unusually stable radical is to be stated.

Concept introduction:

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The process of formation of a dimer, hexaphenylethane from the trityl radicals is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the dimer of two trityl radical, ((4-(diphenylmethylene)cyclohexa-2, 5-dienyl)methanetriyl)tribenzene is formed instead of hexaphenylethane is to be stated.

Concept introduction:

Free radical addition reaction is a reaction in which two stable radicals or a radical and a non radical form a bond by sharing their radicals. The reaction takes place in three steps: chain initiation, chain propagation, and chain termination.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains that the trityl radical is an unusually stable radical because it is stabilized by the resonance effect of the three phenyl rings.

Want to see the full answer?

Chapter 17 Solutions