Chapter 17, Problem 17.3P

Interpretation Introduction

(a)

Interpretation:

The order of relative reactivities of the given compounds in ${\text{S}}_{\text{N}}\text{1}$ solvolysis reaction is to be predicted. The explanation regarding the answer is to be stated.

Concept introduction:

The ${\text{S}}_{\text{N}}\text{1}$ reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster ${\text{S}}_{\text{N}}\text{1}$ reaction.

Interpretation Introduction

(b)

Interpretation:

The order of relative reactivities of the given compounds in ${\text{S}}_{\text{N}}\text{1}$ solvolysis reaction is to be predicted. The explanation regarding your answer is to be stated.

Concept introduction:

The ${\text{S}}_{\text{N}}\text{1}$ reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster ${\text{S}}_{\text{N}}\text{1}$ reaction.