A mechanism has to be proposed for the given rearrangement reaction. Concept introduction: Benzil-benzilic acid rearrangement reaction: Benzil-benzilic acid rearrangement reaction is a base catalysed reaction in which, 1,2-diketones are allowed to react with base followed by the acidification to form α − h y d r o x y c a r b o x y l i c a c i d . Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products. Curved arrows show the bonds that are formed and the bonds that are broken in a reaction. Curved arrows used to understand a reaction mechanism. Electrophile: It is positively charged species which seeks for negative charge and hence accepts pair of electrons from negatively charged species (Nucleophiles) which results in the formation of chemical bond . Nucleophile: It is negatively charged species which seeks for positive charge and hence donate pair of electrons to positively charged species (electrophiles) which results in the formation of chemical bond.

Question

Part A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!

Answer 1

Question

Chapter 17, Problem 17.24P

Interpretation Introduction

Interpretation: A mechanism has to be proposed for the given rearrangement reaction.

Concept introduction:

Benzil-benzilic acid rearrangement reaction:

Benzil-benzilic acid rearrangement reaction is a base catalysed reaction in which,

1,2-diketones are allowed to react with base followed by the acidification to form α−hydroxycarboxylic acid .

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

Curved arrows used to understand a reaction mechanism.

Electrophile: It is positively charged species which seeks for negative charge and hence accepts pair of electrons from negatively charged species (Nucleophiles) which results in the formation of chemical bond.

Nucleophile: It is negatively charged species which seeks for positive charge and hence donate pair of electrons to positively charged species (electrophiles) which results in the formation of chemical bond.

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