ORGANIC CHEMISTRY-EBOOK>I<
9th Edition
ISBN: 9781305084414
Author: McMurry
Publisher: INTER CENG
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Chapter 16.SE, Problem 68AP
Interpretation Introduction
Interpretation:
A mechanism for the reaction of 1-chloroanthraquinone with methoxide ion to give the substitution product 1-methoxyanthraquinone is to be proposed using curved arrows to show the electron flow in each step.
Concept introduction:
Aryl halides that have electron-withdrawing groups undergo nucleophilic substitution reactions. The nucleophile first attacks the electron deficient aryl halide to form a resonance-stabilized, negatively charged intermediate, called Meisenheimer complex which then eliminates a halide ion to yield the product.
To propose:
Using curved arrows to show the electron flow in each step, a mechanism for the reaction of 1-chloroanthraquinone with methoxide ion to give the substitution product 1-methoxyanthraquinone.
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Chapter 16 Solutions
ORGANIC CHEMISTRY-EBOOK>I<
Ch. 16.1 - Prob. 1PCh. 16.2 - Propose a mechanism for the electrophilic...Ch. 16.2 - How many products might be formed on chlorination...Ch. 16.2 - When benzene is treated with D2SŪ4. deuterium...Ch. 16.3 - Prob. 5PCh. 16.3 - What is the major monosubstitution product from...Ch. 16.3 - Identify the carboxylic acid chloride that might...Ch. 16.4 - Rank the compounds in each of the following groups...Ch. 16.4 - Predict the major products of the following...Ch. 16.4 - Prob. 10P
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