a)
Interpretation:
The major product(s) obtainable when chlorobenzene is treated with ethylchloride in the presence of anhydrous AlCl3 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m- position.
To state:
The major product(s) obtainable when chlorobenzene is treated with ethylchloride in the presence of anhydrous AlCl3.
b)
Interpretation:
The major product(s) obtainable when diphenylether is treated with propanoylchloride in the presence of anhydrous AlCl3 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m- position.
To state:
The major product(s) obtainable when diphenylether is treated with propanoylchloride in the presence of anhydrous AlCl3.
c)
Interpretation:
The major product(s) obtainable when benzoic acid is treated with a mixture of HNO3 and H2SO4 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m- position.
To state:
The major product(s) obtainable when benzoic acid is treated with a mixture of HNO3 and H2SO4.
d)
Interpretation:
The major product(s) obtainable when N,N-diethylaminobenzene is treated with SO3 in H2SO4 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m-position.
To state:
The major product(s) obtainable when N,N-diethylaminobenzene is treated with SO3 in H2SO4.

Trending nowThis is a popular solution!

Chapter 16 Solutions
ORGANIC CHEMISTRY-EBOOK>I<
- Steps and explanations pleasearrow_forwardUse diagram to answer the following: 1.Is the overall rxn endo- or exothermic. Explain briefly your answer____________________2. How many steps in this mechanism?_____________3. Which is the rate determining step? Explain briefly your answer____________________4. Identify (circle and label) the reactants,the products and intermediate (Is a Cation, Anion, or a Radical?) Please explain and provide full understanding.arrow_forwardDraw the entire mechanism and add Curved Arrows to show clearly how electrons areredistributed in the process. Please explain and provide steps clearly.arrow_forward
- Match the denticity to the ligand. Water monodentate ✓ C₂O2 bidentate H₂NCH₂NHCH2NH2 bidentate x EDTA hexadentate Question 12 Partially correct Mark 2 out of 2 Flag question Provide the required information for the coordination compound shown below: Na NC-Ag-CN] Number of ligands: 20 Coordination number: 2✔ Geometry: linear Oxidation state of transition metal ion: +3 x in 12 correct out of 2 question Provide the required information for the coordination compound shown below. Na NC-Ag-CN] Number of ligands: 20 Coordination number: 2 Geometry: linear 0 Oxidation state of transition metal ion: +3Xarrow_forwardCan you explain step by step behind what the synthetic strategy would be?arrow_forwardPlease explain step by step in detail the reasoning behind this problem/approach/and answer. thank you!arrow_forward
- 2. Predict the product(s) that forms and explain why it forms. Assume that any necessary catalytic acid is present. .OH HO H₂N OHarrow_forwardconsider the rate of the reaction below to be r. Whats the rate after each reaction? Br + NaCN CN + NaBr a. Double the concentration of alkyl bromide b. Halve the concentration of the electrophile & triple concentration of cyanide c. Halve the concentration of alkyl chloridearrow_forwardPredict the organic reactant that is involved in the reaction below, and draw the skeletal ("line") structures of the missing organic reactant. Please include all steps & drawings & explanations.arrow_forward
