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a)
Interpretation:
The major product(s) obtainable when chlorobenzene is treated with ethylchloride in the presence of anhydrous AlCl3 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m- position.
To state:
The major product(s) obtainable when chlorobenzene is treated with ethylchloride in the presence of anhydrous AlCl3.
b)
Interpretation:
The major product(s) obtainable when diphenylether is treated with propanoylchloride in the presence of anhydrous AlCl3 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m- position.
To state:
The major product(s) obtainable when diphenylether is treated with propanoylchloride in the presence of anhydrous AlCl3.
c)
Interpretation:
The major product(s) obtainable when benzoic acid is treated with a mixture of HNO3 and H2SO4 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m- position.
To state:
The major product(s) obtainable when benzoic acid is treated with a mixture of HNO3 and H2SO4.
d)
Interpretation:
The major product(s) obtainable when N,N-diethylaminobenzene is treated with SO3 in H2SO4 is/are to be stated.
Concept introduction:
The substituents attached to the ring have a strong influence on the incoming electrophile. Electron releasing substituent groups, except halogens, activate the ring and direct the incoming electrophile to the o- and p- positions. Halogens are o- and p- directors but they deactivate the ring. Electron withdrawing substituent groups deactivate the ring and direct the incoming electrophile to the m-position.
To state:
The major product(s) obtainable when N,N-diethylaminobenzene is treated with SO3 in H2SO4.
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Chapter 16 Solutions
EBK ORGANIC CHEMISTRY
- On what basis are Na and Nb ranked against each other?arrow_forwardStep 1: add a curved arrow. Select Draw Templates More / " C H Br 0 Br : :o: Erase H H H H Q2Q Step 2: Draw the intermediates and a curved arrow. Select Draw Templates More MacBook Air / " C H Br 0 9 Q Erase 2Qarrow_forwardO Macmillan Learning Question 23 of 26 > Stacked Step 7: Check your work. Does your synthesis strategy give a substitution reaction with the expected regiochemistry and stereochemistry? Draw the expected product of the forward reaction. - - CN DMF MacBook Air Clearly show stereochemistry. Questionarrow_forward
- NH2 1. CH3–MgCl 2. H3O+ ? As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new C - C bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new C - C bond. Х ☐: Carrow_forwardPredict the major products of this organic reaction. If there will be no major products, check the box under the drawing area instead. No reaction. : + Х è OH K Cr O 2 27 2 4' 2 Click and drag to start drawing a structure.arrow_forwardLaminar compounds are characterized by havinga) a high value of the internal surface of the solid.b) a high adsorption potential.arrow_forward
- Intercalation compounds have their sheetsa) negatively charged.b) positively charged.arrow_forwardIndicate whether the following two statements are correct or not:- Polythiazine, formed by N and S, does not conduct electricity- Carbon can have a specific surface area of 3000 m2/garrow_forwardIndicate whether the following two statements are correct or not:- The S8 heterocycle is the origin of a family of compounds- Most of the elements that give rise to stable heterocycles belong to group d.arrow_forward
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