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Concept explainers
Interpretation: The correct sequence of three consecutive steps which constitutes the hydrolysis of an imine/iminium has to be determined.
Concept introduction:
Amino acids are the molecules containing an
Carbon, hydrogen, oxygen and nitrogen are the key elements in amino acid.
General structure of an amino acid can be drawn as follows,
The transfer of an amino group from an amino acid to a ketoacid with the formation of a new amino acid and a new keto acid is known as transamination reaction.
This reaction is catalysed by a group of enzymes called transaminases or aminotransferases. PLP- Pyridoxalphosphate acts as co-factor in this reaction.
Imines can be obtained by the reaction of an
Simple imines hydrolyze back to the aldehyde or ketone and the amine from which they are originally formed.
Iminium ions on hydrolysis give corresponding amine and ketoacid.
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Chapter 16 Solutions
Organic Chemistry, Loose-leaf Version
- Draw a Newman projection from carbon 3 to carbon 2 in the highest energy conformation for the following molecule. What is this conformation called? What kind of strain is present? Brarrow_forwardWhich of the following dienophiles is most reactive in a Diels-Alder reaction: Please explain why the correct answer to this question is option 5. Please provide a detailed explanation.arrow_forwardWhich of the following would you expect to be aromatic? Please provide a detailed explanation.arrow_forward
- Draw the enantiomer and diastereomers of the following molecule. Label each type of stereoisomers. Label each chiral center as R or S. HOarrow_forwardWhich diene and dienophile would you choose to synthesize the following compound? Please provide a detailed explanation. Please include a drawing showing the mechanism of the synthesis. Please also explain why it is the correct diene and dienophile.arrow_forwardUsing the sketcher below, draw the structure of N-ethyldecylamine. Answer: 0 ୨୫) . 始 {n [ ]t ?arrow_forward
- Which of the following would you expect to be aromatic? Please provide a detailed explanation.arrow_forwardIdentify the characteristic signals that you would expect in the diagnostic region of an IR spectrum of each of the following compounds. a. H₂N b.arrow_forwardWhat is the lowest energy chair for the following cyclohexane? ' || || a. b. " " d.arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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