Concept explainers
Which is true for any polyprotic acid?
a)
b)
c)
d)
e)
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- How is acid strength related to the value of Ka? What is the difference between strong acids and weak acids (see Table 13-1)? As the strength of an acid increases, what happens to the strength of the conjugate base? How is base strength related to the value of Kb? As the strength of a base increases, what happens to the strength of the conjugate acid?arrow_forwardUsing the diagrams shown in Problem 10-37, which of the four acids is the weakest acid?arrow_forwardWhich is the stronger of the following two acids? (a) acetic acid, CH3CO2H, Ka = 1.8 105 (b) chloroacetic acid, ClCH2CO2H, pKa = 2.85arrow_forward
- Use Table 13-3 to help answer the following questions. a. Which is the stronger base, ClO4 or C6H5NH2? b. Which is the stronger base, H2O or C6H5NH2? c. Which is the stronger base, OH or C6H5NH2? d. Which is the stronger base, C6H5NH2 or CH3NH2?arrow_forwardUsing your results from Exercise 133, place the species in each of the following groups in order of increasing base strength. a. OH, SH, SeH b. NH3, PH3 c. NH3, HONH2arrow_forwardThe pH of a 0.10-M solution of caffeine is 11.16. Determine Kb for caffeine from these data: C8H10N4O2(aq)+H2O(l)C8H10N4O2H+(aq)+OH(aq)arrow_forward
- Consider the following four solutions: (1) apple juice, pH 3.8, (2) pickle juice, pH 3.5, (3) carbonated beverage, pH 3.0, and (4) drinking water, pH 7.2. a. Which solution has the highest [H3O+]? b. Which solution has the highest [OH]? c. List the solutions in order of increasing acidity. d. List the solutions in order of decreasing basicity.arrow_forwardWrite equations that show H2PO4- acting both as an acid and as a base.arrow_forwardBarbituric acid, HC4H3N2O3, is used to prepare barbiturates, a class of drugs used as sedatives. Its Ka is 9.8105. Calculate [H+] in solutions prepared by adding enough water to the following to make 1.45 L. (a) 0.344 mol (b) 28.9 garrow_forward
- 8-17 For each of the following, tell whether the base is strong or weak. (a) NaOH (b) Sodium acetate (c) KOH (d) Ammonia (e) Waterarrow_forwardPlace the species in each of the following groups in order of increasing acid strength. a. H2O, H2S, H2Se (bond energies: HO, 467 kJ/mol; HS, 363 kJ/mol; HSe, 276 kJ/mol) b. CH3CO2H, FCH2CO2H, F2CHCO2H, F3CCO2H c. NH4+, HONH3+ d. NH4+, PH4+ (bond energies: NH, 391 kJ/mol; PH, 322 kJ/mol) Give reasons for the orders you chose.arrow_forwardConsider a 0.67-M solution of C2H5NH2 (Kb = 5.6 104). a. Which of the following are major species in the solution? i. C2H5NH2 ii. H+ iii. OH iv. H2O v. C2H5NH3+ b. Calculate the pH of this solution.arrow_forward
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