(a) Interpretation: The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent. Concept Introduction: Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde . This reagent converts aldehyde into a carboxylic acid . In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

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Answer 1

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Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400

• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

Could you redraw these and also explain how to solve them for me pleas

Answer 2

Question

Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

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Answer 3

Question

Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

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Answer 4

Question

Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

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Answer 5

Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Answer 6

Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Answer 7

Chapter 16.5, Problem 16.9P

Interpretation Introduction

(a)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The constitutional isomer of 3-heptanone must be drawn that reacts with Tollens reagent.

Concept Introduction:

Tollens reagent is a mixture of silver nitrate, sodium hydroxide, and ammonia. It is used in the laboratory to analyze the presence of aldehyde. This reagent converts aldehyde into a carboxylic acid. In the silver mirror's test, Tollens reagent is used to identify the functional group on the molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - Prob. 16.1P Ch. 16.1 - Draw the structure of the three constitutional...Ch. 16.2 - Give the IUPAC name for each aldehyde. a. (...Ch. 16.2 - Give the structure corresponding to each TUPAC...Ch. 16.2 - Prob. 16.4P Ch. 16.2 - Prob. 16.2PP Ch. 16.2 - Give the structure corresponding to each name. a....Ch. 16.3 - Which compound in each pair has the higher boiling...Ch. 16.3 - Acetone and progesterone are two ketones that...Ch. 16.4 - Prob. 16.8P

Solution Summary: The author explains that the constitutional isomer of 3-heptanone must be drawn that does not react with Tollens reagent.

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