Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 16.5, Problem 16.13P

(a)

Interpretation Introduction

Interpretation:

The given reaction equation should be completed.

Concept introduction:

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

Fundamentals of General, Organic, and Biological Chemistry (8th Edition), Chapter 16.5, Problem 16.13P , additional homework tip  1

In a quaternary ammonium ion a nitrogen atom with four attached groups is positively charged. And their compounds are known as quaternary ammonium salt.

Reactions of these types of amine with HX can be simply represented as follows,

RNH2Primaryamine+HXRN+H3XAlkylammoniumhalideR2NHSecondaryamine+HXR2N+H2XDialkylammoniumhalideR3NTertiaryamine+HXR2N+H2XTrialkylammoniumhalide

(b)

Interpretation Introduction

Interpretation:

The given reaction equation should be completed.

Concept introduction:

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

Fundamentals of General, Organic, and Biological Chemistry (8th Edition), Chapter 16.5, Problem 16.13P , additional homework tip  2

In a quaternary ammonium ion a nitrogen atom with four attached groups is positively charged. And their compounds are known as quaternary ammonium salt.

Reactions of these types of amine with HX can be simply represented as follows,

RNH2Primaryamine+HXRN+H3XAlkylammoniumhalideR2NHSecondaryamine+HXR2N+H2XDialkylammoniumhalideR3NTertiaryamine+HXR2N+H2XTrialkylammoniumhalide

(c)

Interpretation Introduction

Interpretation:

The given reaction equation should be completed.

Concept introduction:

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

Fundamentals of General, Organic, and Biological Chemistry (8th Edition), Chapter 16.5, Problem 16.13P , additional homework tip  3

In a quaternary ammonium ion a nitrogen atom with four attached groups is positively charged. And their compounds are known as quaternary ammonium salt.

Reactions of these types of amine with HX can be simply represented as follows,

RNH2Primaryamine+HXRN+H3XAlkylammoniumhalideR2NHSecondaryamine+HXR2N+H2XDialkylammoniumhalideR3NTertiaryamine+HXR2N+H2XTrialkylammoniumhalide

(d)

Interpretation Introduction

Interpretation:

The given reaction equation should be completed.

Concept introduction:

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

Fundamentals of General, Organic, and Biological Chemistry (8th Edition), Chapter 16.5, Problem 16.13P , additional homework tip  4

In a quaternary ammonium ion a nitrogen atom with four attached groups is positively charged. And their compounds are known as quaternary ammonium salt.

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Chapter 16 Solutions

Fundamentals of General, Organic, and Biological Chemistry (8th Edition)

Ch. 16.4 - Prob. 16.11PCh. 16.5 - Write an equation for the acid-base equilibrium...Ch. 16.5 - Prob. 16.13PCh. 16.5 - Prob. 16.14PCh. 16.5 - Prob. 16.15PCh. 16.5 - Prob. 16.16PCh. 16.6 - Prob. 16.17PCh. 16.6 - Prob. 16.18PCh. 16.6 - Prob. 16.19PCh. 16.6 - Prob. 16.20PCh. 16.6 - Prob. 16.21PCh. 16.6 - Prob. 16.22PCh. 16.7 - Prob. 16.1CIAPCh. 16.7 - Prob. 16.2CIAPCh. 16.7 - Prob. 16.3CIAPCh. 16 - (a) For the compound above, identify each nitrogen...Ch. 16 - The structure of the amino acid lysine (in its...Ch. 16 - Prob. 16.25UKCCh. 16 - Prob. 16.26UKCCh. 16 - Prob. 16.27UKCCh. 16 - Complete the following equations: (a) (b)...Ch. 16 - Prob. 16.29APCh. 16 - Draw the structures corresponding to the following...Ch. 16 - Name the following amines, and classify them as...Ch. 16 - Name the following amines, and identify them as...Ch. 16 - Prob. 16.33APCh. 16 - Which is a stronger base, diethyl ether or...Ch. 16 - Prob. 16.35APCh. 16 - Prob. 16.36APCh. 16 - The compound lidocaine is used medically as a...Ch. 16 - Prob. 16.38APCh. 16 - Draw the structures of the ammonium ions formed...Ch. 16 - Prob. 16.40APCh. 16 - Prob. 16.41APCh. 16 - Prob. 16.42APCh. 16 - Prob. 16.43APCh. 16 - Prob. 16.44APCh. 16 - Prob. 16.45CPCh. 16 - Prob. 16.46CPCh. 16 - Prob. 16.47CPCh. 16 - Prob. 16.48CPCh. 16 - How do amines differ from analogous alcohols in...Ch. 16 - Name at least two undesirable characteristics are...Ch. 16 - Prob. 16.52CPCh. 16 - Complete the following equations (Hint: Answers...Ch. 16 - Prob. 16.54CPCh. 16 - Prob. 16.55CPCh. 16 - Why is cyclohexylamine not considered to be a...Ch. 16 - Prob. 16.57CPCh. 16 - Prob. 16.58GPCh. 16 - 1-Propylamine, 1-propanol, acetic acid, and butane...Ch. 16 - Prob. 16.60GPCh. 16 - Lemon juice, which contains citric acid, is...
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