General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
5th Edition
ISBN: 9780321967466
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 16.1, Problem 16.1QAP
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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
.
3°C
with
TH
12. (10pts total) Provide the major product for each reaction depicted below. If no reaction
occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction.
3H
24 total (30)
24
21
2h
• 6H total
● 8H total
34
래
Br2
hv
major product
will be most
Substituted
12
hv
Br
NR
I too weak of a
participate in P-1
F₂
hv
Statistically
most favored
product will be
major
=
most subst =
thermo favored
hydrogen atom abstractor to
LL
F
Five chemistry project topic that does not involve practical
Chapter 16 Solutions
General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
Ch. 16.1 - What carboxylic acid is responsible for the pain...Ch. 16.1 - What carboxylic acid is found in vinegar?Ch. 16.1 - Prob. 16.3QAPCh. 16.1 - Draw the condensed structural formula and give the...Ch. 16.1 - Prob. 16.5QAPCh. 16.1 - Prob. 16.6QAPCh. 16.1 - Draw the condensed structural formula for each of...Ch. 16.1 - Prob. 16.8QAPCh. 16.1 - Prob. 16.9QAPCh. 16.1 - Prob. 16.10QAP
Ch. 16.2 - Prob. 16.11QAPCh. 16.2 - Prob. 16.12QAPCh. 16.2 - Prob. 16.13QAPCh. 16.2 - Prob. 16.14QAPCh. 16.2 - Prob. 16.15QAPCh. 16.2 - Prob. 16.16QAPCh. 16.2 - Prob. 16.17QAPCh. 16.2 - Prob. 16.18QAPCh. 16.2 - Prob. 16.19QAPCh. 16.2 - Prob. 16.20QAPCh. 16.3 - Prob. 16.21QAPCh. 16.3 - Prob. 16.22QAPCh. 16.3 - Prob. 16.23QAPCh. 16.3 - Prob. 16.24QAPCh. 16.3 - Prob. 16.25QAPCh. 16.3 - Prob. 16.26QAPCh. 16.3 - 16.27 Give the IUPAC and common names,if any, of...Ch. 16.3 - Prob. 16.28QAPCh. 16.4 - Prob. 16.29QAPCh. 16.4 - Prob. 16.30QAPCh. 16.4 - Prob. 16.31QAPCh. 16.4 - Prob. 16.32QAPCh. 16.4 - Prob. 16.33QAPCh. 16.4 - Prob. 16.34QAPCh. 16.5 - Prob. 16.35QAPCh. 16.5 - Prob. 16.36QAPCh. 16.5 - Prob. 16.37QAPCh. 16.5 - Prob. 16.38QAPCh. 16.5 - Prob. 16.39QAPCh. 16.5 - Prob. 16.40QAPCh. 16 - Prob. 16.41UTCCh. 16 - Prob. 16.42UTCCh. 16 - Prob. 16.43UTCCh. 16 - Prob. 16.44UTCCh. 16 - Prob. 16.45UTCCh. 16 - Prob. 16.46UTCCh. 16 - Give the IUPAC and common names, if any, for each...Ch. 16 - Prob. 16.48AQAPCh. 16 - Prob. 16.49AQAPCh. 16 - Prob. 16.50AQAPCh. 16 - Prob. 16.51AQAPCh. 16 - Prob. 16.52AQAPCh. 16 - Prob. 16.53AQAPCh. 16 - Prob. 16.54AQAPCh. 16 - Prob. 16.55AQAPCh. 16 - Prob. 16.56AQAPCh. 16 - Prob. 16.57AQAPCh. 16 - Prob. 16.58AQAPCh. 16 - Prob. 16.59AQAPCh. 16 - Prob. 16.60AQAPCh. 16 - Prob. 16.61AQAPCh. 16 - Prob. 16.62AQAPCh. 16 - Prob. 16.63AQAPCh. 16 - Prob. 16.64AQAPCh. 16 - Prob. 16.65CQCh. 16 - Prob. 16.66CQCh. 16 - Prob. 16.67CQCh. 16 - Prob. 16.68CQCh. 16 - Prob. 16.69CQCh. 16 - Prob. 16.70CQ
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- Please correct answer and don't used hand raitingarrow_forwardQ2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.arrow_forward13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Googlearrow_forward
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