Introduction To Chemistry
Introduction To Chemistry
5th Edition
ISBN: 9781259911149
Author: BAUER, Richard C., Birk, James P., Marks, Pamela
Publisher: Mcgraw-hill Education,
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Chapter 16, Problem 76QP
Interpretation Introduction

Interpretation:

The comparison of the boiling points of diethyl ether and butanol is to be determined.

Concept Introduction:

The boiling point of a molecule depends on the structure of it and the functional group present. Hydrogen bonding plays an important role in determining boiling point as it is a strong intermolecular force of attraction.

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5. Use the MS data to answer the questions on the next page. 14.0 1.4 15.0 8.1 100- MS-IW-5644 26.0 2.8 27.0 6.7 28.0 1.8 29.0 80 4.4 38.0 1.0 39.0 1.5 41.0 1.2 42.0 11.2 43.0 100.0 44.0 4.3 79.0 1.9 80.0 2.6 Relative Intensity 40 81.0 1.9 82.0 2.5 93.0 8.7 20- 95.0 8.2 121.0 2.0 123.0 2.0 136.0 11.8 0 138.0 11.5 20 40 8. 60 a. Br - 0 80 100 120 140 160 180 200 220 m/z Identify the m/z of the base peak and molecular ion. 2 b. Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0, 95.0, 136.0, and 138.0 m/z. C. Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to fragment 43.0 m/z. Be sure to include all electrons and formal charges. 6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium ion (CsH6N) and show your work.
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Stereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)

Chapter 16 Solutions

Introduction To Chemistry

Ch. 16 - Prob. 2PPCh. 16 - Prob. 3PPCh. 16 - Prob. 4PPCh. 16 - Prob. 5PPCh. 16 - Prob. 6PPCh. 16 - Prob. 7PPCh. 16 - Prob. 8PPCh. 16 - Prob. 9PPCh. 16 - Prob. 10PPCh. 16 - Prob. 11PPCh. 16 - Prob. 1QPCh. 16 - Prob. 2QPCh. 16 - Prob. 3QPCh. 16 - Prob. 4QPCh. 16 - Prob. 5QPCh. 16 - Prob. 6QPCh. 16 - Prob. 7QPCh. 16 - Prob. 8QPCh. 16 - Prob. 9QPCh. 16 - Prob. 10QPCh. 16 - Prob. 11QPCh. 16 - Prob. 12QPCh. 16 - Prob. 13QPCh. 16 - Prob. 14QPCh. 16 - Prob. 15QPCh. 16 - Prob. 16QPCh. 16 - Prob. 17QPCh. 16 - Prob. 18QPCh. 16 - Prob. 19QPCh. 16 - Prob. 20QPCh. 16 - Prob. 21QPCh. 16 - Prob. 22QPCh. 16 - Prob. 23QPCh. 16 - Prob. 24QPCh. 16 - Prob. 25QPCh. 16 - Prob. 26QPCh. 16 - Prob. 27QPCh. 16 - Prob. 28QPCh. 16 - Prob. 29QPCh. 16 - Prob. 30QPCh. 16 - Prob. 31QPCh. 16 - Prob. 32QPCh. 16 - Prob. 33QPCh. 16 - Prob. 34QPCh. 16 - Prob. 35QPCh. 16 - Prob. 36QPCh. 16 - Prob. 37QPCh. 16 - Prob. 38QPCh. 16 - Prob. 39QPCh. 16 - Prob. 40QPCh. 16 - Prob. 41QPCh. 16 - Write IUPAC names for the following compounds....Ch. 16 - Prob. 43QPCh. 16 - Prob. 44QPCh. 16 - Prob. 45QPCh. 16 - Prob. 46QPCh. 16 - Prob. 47QPCh. 16 - Prob. 48QPCh. 16 - Prob. 49QPCh. 16 - Prob. 50QPCh. 16 - Prob. 51QPCh. 16 - Prob. 52QPCh. 16 - Prob. 53QPCh. 16 - Prob. 54QPCh. 16 - Prob. 55QPCh. 16 - Prob. 56QPCh. 16 - Prob. 57QPCh. 16 - Prob. 58QPCh. 16 - Prob. 59QPCh. 16 - Prob. 60QPCh. 16 - Prob. 61QPCh. 16 - Prob. 62QPCh. 16 - Prob. 63QPCh. 16 - Prob. 64QPCh. 16 - Prob. 65QPCh. 16 - Prob. 66QPCh. 16 - Prob. 67QPCh. 16 - Prob. 68QPCh. 16 - Prob. 69QPCh. 16 - Prob. 70QPCh. 16 - Prob. 71QPCh. 16 - Prob. 72QPCh. 16 - Prob. 73QPCh. 16 - Prob. 74QPCh. 16 - Prob. 75QPCh. 16 - Prob. 76QPCh. 16 - Prob. 77QPCh. 16 - Prob. 78QPCh. 16 - Prob. 79QPCh. 16 - Prob. 80QPCh. 16 - Prob. 81QPCh. 16 - Prob. 82QPCh. 16 - Prob. 83QPCh. 16 - Prob. 84QPCh. 16 - Prob. 85QPCh. 16 - Prob. 86QPCh. 16 - Prob. 87QPCh. 16 - Prob. 88QPCh. 16 - Predict and explain the relative boiling points of...Ch. 16 - Prob. 90QPCh. 16 - Prob. 91QPCh. 16 - Prob. 92QPCh. 16 - Prob. 93QPCh. 16 - Prob. 94QPCh. 16 - Prob. 95QPCh. 16 - Prob. 96QPCh. 16 - Prob. 97QPCh. 16 - Prob. 98QPCh. 16 - Prob. 99QPCh. 16 - Prob. 100QPCh. 16 - Prob. 101QPCh. 16 - Prob. 102QPCh. 16 - Prob. 103QPCh. 16 - Prob. 104QPCh. 16 - Prob. 105QPCh. 16 - Prob. 106QPCh. 16 - Prob. 107QPCh. 16 - Prob. 108QPCh. 16 - Prob. 109QPCh. 16 - Prob. 110QPCh. 16 - Prob. 111QPCh. 16 - Prob. 112QPCh. 16 - Prob. 113QPCh. 16 - Prob. 114QPCh. 16 - Prob. 115QPCh. 16 - Prob. 116QPCh. 16 - Prob. 117QPCh. 16 - Prob. 118QPCh. 16 - Prob. 119QPCh. 16 - Prob. 120QPCh. 16 - Prob. 121QPCh. 16 - Draw the line structures for the ether and two...Ch. 16 - Prob. 123QPCh. 16 - Prob. 124QPCh. 16 - Prob. 125QPCh. 16 - Prob. 126QPCh. 16 - Write structural formulas for all the isomers of...Ch. 16 - Prob. 128QPCh. 16 - Prob. 129QPCh. 16 - Prob. 130QPCh. 16 - Prob. 131QPCh. 16 - Prob. 132QPCh. 16 - Prob. 133QPCh. 16 - Prob. 134QPCh. 16 - Prob. 135QPCh. 16 - Prob. 136QPCh. 16 - Prob. 137QPCh. 16 - Prob. 138QPCh. 16 - Prob. 139QPCh. 16 - Prob. 140QPCh. 16 - Prob. 141QPCh. 16 - Prob. 142QPCh. 16 - Prob. 143QP
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